A new enzyme model for enantioselective esterases based on molecularly imprinted polymers

Chemistry - A European Journal

Volumn 9, Issue 17, 2003, Pages 4106-4117

  Emgenbroich, Marco ^a   Wulff, Günter ^a  

^a HEINRICH HEINE UNIVERSITY   (Germany)

Author keywords

Enantioselectivity; Enzyme catalysis; Enzyme models; Molecular imprinting; Transition state analogue

Indexed keywords

CATALYSTS; ENZYME INHIBITION; ENZYMES; ESTERS; HYDROLYSIS; POLYMERIZATION; STOICHIOMETRY; SUBSTRATES; SYNTHESIS (CHEMICAL);

MOLECULAR IMPRINTING;

ORGANIC POLYMERS;

AMIDINE; ENZYME; ESTER DERIVATIVE; ESTERASE; N (4 CARBOXYBENZOYL) 1 AMINO 3 METHYLBUTYLPHOSPHONIC ACID 3,5 DIMETHYLPHENYL ESTER; N TEREPHTHALOYL DEXTRO LEUCINE 3,5 DIMETHYLPHENYL ESTER; N TEREPHTHALOYL DEXTRO VALINE 3,5 DIMETHYLPHENYL ESTER; N TEREPHTHALOYLLEUCINE 3,5 DIMETHYLPHENYL ESTER; N TEREPHTHALOYLVALINE 3,5 DIMETHYLPHENYL ESTER; PHOSPHONIC ACID ESTER; POLYMER; UNCLASSIFIED DRUG;

ARTICLE; CALCULATION; CARBON NUCLEAR MAGNETIC RESONANCE; CATALYSIS; CATALYST; CHEMICAL INTERACTION; COVALENT BOND; ENANTIOMER; ENANTIOSELECTIVITY; ENZYME ACTIVITY; HYDROLYSIS; KINETICS; MICHAELIS CONSTANT; MOLECULAR IMPRINTING; PHASE TRANSITION; POLYMERIZATION; PROTON NUCLEAR MAGNETIC RESONANCE; STOICHIOMETRY; SYNTHESIS; VELOCITY;

BUFFERS; CATALYSIS; ESTERASES; HYDROLYSIS; KINETICS; LEUCINE; MOLECULAR CONFORMATION; MOLECULAR STRUCTURE; POLYMERS; STEREOISOMERISM; VALINE;

EID: 0141649386     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/chem.200304783     Document Type: Article

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