Molecularly imprinted polymers having amidine and imidazole functional groups as an enzyme-mimetic catalyst for ester hydrolysis

Macromolecular Research

Volumn 10, Issue 2, 2002, Pages 122-126

  Chen, Wen ^a   Han, Dong Keun ^a   Ahn, Kwang Duk ^a   Kim, Jong Man ^b  

^a Korea Institute of Science and Technology   (South Korea)

^b Hanyang University   (South Korea)

Author keywords

Amidine functional; Enzyme mimetic reaction; Imidazole functional; Molecularly imprinted polymers; Molecularly imprinting catalysts; Transition state analogue imprinting

Indexed keywords

4 NITROPHENYL PHOSPHATE; 4 NITROPHENYLACETIC ACID; 4 NITROPHENYLMETHYLCARBONATE; ACETIC ACID DERIVATIVE; AMIDINE; BUFFER; CARBONIC ACID DERIVATIVE; ENZYME; ESTER; FUNCTIONAL GROUP; IMIDAZOLE; POLYMER; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CATALYST; CHEMICAL REACTION; COMPARATIVE STUDY; ENZYME ACTIVITY; ENZYME SUBSTRATE; HYDROLYSIS; MOLECULAR IMPRINTING; PH; POLYMERIZATION; SYNTHESIS;

EID: 0038699594     PISSN: 15985032     EISSN: None     Source Type: Journal    
DOI: 10.1007/BF03218301     Document Type: Article

References (26)

1. G. Wulff, Chem. Rev., 102, 1 (2002); Angew. Chem. Int. Ed. Engl., 34, 1812 (1995); Chemtech., 19, 19 (November 1998).
2. G. Wulff, Chem. Rev., 102, 1 (2002); Angew. Chem. Int. Ed. Engl., 34, 1812 (1995); Chemtech., 19, 19 (November 1998).
3. G. Wulff, Chem. Rev., 102, 1 (2002); Angew. Chem. Int. Ed. Engl., 34, 1812 (1995); Chemtech., 19, 19 (November 1998).
4. K.-D. Ahn and J.-M. Kim, Polymer Sci. & Technol. (Korean), 9, 137 (1998) and 11, 332 (2000).
5. K.-D. Ahn and J.-M. Kim, Polymer Sci. & Technol. (Korean), 9, 137 (1998) and 11, 332 (2000).
6. F. L. Dicker and O. Hayden, Adv. Mater., 12, 311 (2000); S. Piletsky, S. Alcock, and A. R. F. Turner, Trend Biotech., 19, 9 (2001).
7. F. L. Dicker and O. Hayden, Adv. Mater., 12, 311 (2000); S. Piletsky, S. Alcock, and A. R. F. Turner, Trend Biotech., 19, 9 (2001).
8. B. Sellergren, Angew. Chem. Int. Ed. Engl., 39, 1031 (2000).
9. M. Whitcomb and E. N. Vulfson, Adv. Mater., 13, 467 (2000).
10. H. Asansuma, T. Hishiya, and M. Komiyama, Adv. Mater., 12, 1019 (2000).
11. A. Kugimiya, Y. Kuwada, and T. Takeuchi, J. Chromatogr. A, 938, 131 (2001).
12. O. Kriz, O. Ramstrom, and K. Mosbach, Anal. Chem., 69, 345A (1997).
13. R. A. Lerner, S. J. Benkvoic, and P. G. Schultz, Science, 252, 659 (1991).
14. A. Leonhardt and K. Mosbach, React. Polym., 6, 285 (1987); D. K. Robinson and K. Mosbach, J. Chem. Soc., Chem. Commun., 969 (1989).
15. A. Leonhardt and K. Mosbach, React. Polym., 6, 285 (1987); D. K. Robinson and K. Mosbach, J. Chem. Soc., Chem. Commun., 969 (1989).
16. K. Ohkubo, Y. Urata, S. Hirota, Y. Honda, Y. Fujishita, and T. Sagawa, J. Mol. Catal., 87, L21 (1994).
17. J. V. Beach and K. J. Shea, J. Am. Chem. Soc., 116, 379 (1994).
18. B. Sellergren, R. N. Karmalkar, and K. J. Shea, J. Org. Chem., 65, 4009 (2000).
19. J.-M. Kim, K.-D. Ahn, and G. Wulff, Macromol. Chem. Phys., 202, 1105 (2001).
20. A. G. Strikovsky, D. Kasper, M. Grün, B. S. Green, J. Hradil, and G. Wulff, J. Am. Chem. Soc., 122, 6295 (2000).
21. G. Wulff, T. Gross, and R. Schönfeld, Angew. Chem. Int. Ed. Engl., 36, 1962 (1997).
22. J.-M. Kim, K.-D. Ahn, G. Strikovsky, and G. Wulff, Bull. Korean Chem. Soc., 22, 689 (2001).
23. G. Wulff and R. Schönfeld, Adv. Mater., 10, 957 (1998)
24. C. G. Overberger, T. St. Pierre, N. Vorchheimer, J. Lee, and S. Yaroslavsky, J. Am. Chem. Soc., 87, 296 (1969).
25. B. S. Lee, M. G. Kulkarni, and R. A. Mashelkar, React. & Func. Polym., 39, 37 (1999).
26. H. Dugas, Bioorganic Chemistry, Third Ed., Springer-Verlag, New York, USA, 1996, pp 192.