The v(CO) vibrational spectra of planar transition metal carbonyl clusters

Inorganic Chemistry

Volumn 42, Issue 20, 2003, Pages 6314-6322

  Kettle, S F A ^a   Boccaleri, E ^b   Diana, E ^c   Rossetti, R ^c   Stanghellini, P L ^b   Iapalucci, M C ^d   Longoni, G ^d  

^a UNIVERSITY OF EAST ANGLIA   (United Kingdom)

^b UNIVERSITY OF EASTERN PIEDMONT   (Italy)

^c UNIVERSITY OF TURIN   (Italy)

^d UNIVERSITY OF BOLOGNA   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

CARBON MONOXIDE; CARBONYL DERIVATIVE; TRANSITION ELEMENT;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL STRUCTURE; INFRARED SPECTROMETRY; MOLECULAR MODEL; QUALITATIVE ANALYSIS; RAMAN SPECTROMETRY; VIBRATION;

EID: 0141646605     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic034477y     Document Type: Article

References (46)

1. Tenne, R. Prog. Inorg. Chem. 2001, 50, 269. Shvartsburg, A. A.; Hudgins, R. R.; Dugourd, P.; Jarrold, M. F. Chem. Soc. Rev. 2001, 30, 26. Driess, M. Adv. Inorg. Chem. 2000, 50, 235. Mitzi, D. B. Prog. Inorg. Chem. 1999, 48, 1.
2. Tenne, R. Prog. Inorg. Chem. 2001, 50, 269. Shvartsburg, A. A.; Hudgins, R. R.; Dugourd, P.; Jarrold, M. F. Chem. Soc. Rev. 2001, 30, 26. Driess, M. Adv. Inorg. Chem. 2000, 50, 235. Mitzi, D. B. Prog. Inorg. Chem. 1999, 48, 1.
3. Tenne, R. Prog. Inorg. Chem. 2001, 50, 269. Shvartsburg, A. A.; Hudgins, R. R.; Dugourd, P.; Jarrold, M. F. Chem. Soc. Rev. 2001, 30, 26. Driess, M. Adv. Inorg. Chem. 2000, 50, 235. Mitzi, D. B. Prog. Inorg. Chem. 1999, 48, 1.
4. Tenne, R. Prog. Inorg. Chem. 2001, 50, 269. Shvartsburg, A. A.; Hudgins, R. R.; Dugourd, P.; Jarrold, M. F. Chem. Soc. Rev. 2001, 30, 26. Driess, M. Adv. Inorg. Chem. 2000, 50, 235. Mitzi, D. B. Prog. Inorg. Chem. 1999, 48, 1.
5. Wong, M. W. Chem. Phys. Lett. 1996, 256, 391. Jang, J. H.; Lee, J. G.; Lee, H.; Xie, Y.; Schafer, H. F., III. J. Phys. Chem. A 1998, 102, 5298. Chermette, H. Coord. Chem. Rev. 1998, 178-180, 699. Schettino, V.; Pagliai, M.; Ciabini, L.; Cardini, G. J. Phys. Chem. A 2001, 105, 11192.
6. Wong, M. W. Chem. Phys. Lett. 1996, 256, 391. Jang, J. H.; Lee, J. G.; Lee, H.; Xie, Y.; Schafer, H. F., III. J. Phys. Chem. A 1998, 102, 5298. Chermette, H. Coord. Chem. Rev. 1998, 178-180, 699. Schettino, V.; Pagliai, M.; Ciabini, L.; Cardini, G. J. Phys. Chem. A 2001, 105, 11192.
7. Wong, M. W. Chem. Phys. Lett. 1996, 256, 391. Jang, J. H.; Lee, J. G.; Lee, H.; Xie, Y.; Schafer, H. F., III. J. Phys. Chem. A 1998, 102, 5298. Chermette, H. Coord. Chem. Rev. 1998, 178-180, 699. Schettino, V.; Pagliai, M.; Ciabini, L.; Cardini, G. J. Phys. Chem. A 2001, 105, 11192.
8. Wong, M. W. Chem. Phys. Lett. 1996, 256, 391. Jang, J. H.; Lee, J. G.; Lee, H.; Xie, Y.; Schafer, H. F., III. J. Phys. Chem. A 1998, 102, 5298. Chermette, H. Coord. Chem. Rev. 1998, 178-180, 699. Schettino, V.; Pagliai, M.; Ciabini, L.; Cardini, G. J. Phys. Chem. A 2001, 105, 11192.
9. Haines, L. H.; Stiddard, M. H. B. Adv. Inorg. Chem. Radiochem. 1969, 12, 53. Kettle, S. F. A. Top. Curr. Chem. 1977, 71, 111.
10. Haines, L. H.; Stiddard, M. H. B. Adv. Inorg. Chem. Radiochem. 1969, 12, 53. Kettle, S. F. A. Top. Curr. Chem. 1977, 71, 111.
11. Kettle, S. F. A.; Diana, E.; Rossetti, R.; Stanghellini, P. L. Inorg. Chem. 1998, 37, 6502.
12. Kettle, S. F. A.; Diana, E.; Rossetti, R.; Stanghellini, P. L. J. Am. Chem. Soc. 1997, 119, 8228.
13. Pierce, N. A.; Sheppard, N. Surf. Sci. 1976, 59, 205. Sheppard, N.; Erkenlens, J. Appl. Spectrosc. 1984, 38, 471. Chabal, Y. J. Surf. Sci. Rep. 1988, 8, 211. Kettle, S. F. A. THEOCHEM 1995, 341, 25.
14. Pierce, N. A.; Sheppard, N. Surf. Sci. 1976, 59, 205. Sheppard, N.; Erkenlens, J. Appl. Spectrosc. 1984, 38, 471. Chabal, Y. J. Surf. Sci. Rep. 1988, 8, 211. Kettle, S. F. A. THEOCHEM 1995, 341, 25.
15. Pierce, N. A.; Sheppard, N. Surf. Sci. 1976, 59, 205. Sheppard, N.; Erkenlens, J. Appl. Spectrosc. 1984, 38, 471. Chabal, Y. J. Surf. Sci. Rep. 1988, 8, 211. Kettle, S. F. A. THEOCHEM 1995, 341, 25.
16. Pierce, N. A.; Sheppard, N. Surf. Sci. 1976, 59, 205. Sheppard, N.; Erkenlens, J. Appl. Spectrosc. 1984, 38, 471. Chabal, Y. J. Surf. Sci. Rep. 1988, 8, 211. Kettle, S. F. A. THEOCHEM 1995, 341, 25.
17. Kettle, S. F. A. Spectrochim. Acta A 1998, 54A, 1639.
18. Kettle, S. F. A.; Diana, E.; Boccaleri, E.; Stanghellini, P. L. Eur. J. Inorg. Chem. 1999, 1957.
19. Kettle, S. F. A.; Boccaleri, E.; Diana, E.; Rossetti, R.; Stanghellini, P. L.; lapalucci, M. C.; Longoni, G. J. Cluster Sci. 2001, 12, 175.
20. Malinek, S. M.; Coucouvanis, D. Prog. Inorg. Chem. 2001, 49, 599.
21. Turner, J. W.; Schultz, F. A. Coord. Chem. Rev. 2001, 219-221, 81. Launay, J. P. Chem. Soc. Rev. 2001, 30, 386. Cornia, A.; Gatteschi, D.; Sessoli, R. Coord. Chem Rev. 2001, 219-221, 573. Winpenny, R. E. P. Adv. Inorg. Chem. 2001, 52, 1.
22. Turner, J. W.; Schultz, F. A. Coord. Chem. Rev. 2001, 219-221, 81. Launay, J. P. Chem. Soc. Rev. 2001, 30, 386. Cornia, A.; Gatteschi, D.; Sessoli, R. Coord. Chem Rev. 2001, 219-221, 573. Winpenny, R. E. P. Adv. Inorg. Chem. 2001, 52, 1.
23. Turner, J. W.; Schultz, F. A. Coord. Chem. Rev. 2001, 219-221, 81. Launay, J. P. Chem. Soc. Rev. 2001, 30, 386. Cornia, A.; Gatteschi, D.; Sessoli, R. Coord. Chem Rev. 2001, 219-221, 573. Winpenny, R. E. P. Adv. Inorg. Chem. 2001, 52, 1.
24. Turner, J. W.; Schultz, F. A. Coord. Chem. Rev. 2001, 219-221, 81. Launay, J. P. Chem. Soc. Rev. 2001, 30, 386. Cornia, A.; Gatteschi, D.; Sessoli, R. Coord. Chem Rev. 2001, 219-221, 573. Winpenny, R. E. P. Adv. Inorg. Chem. 2001, 52, 1.
25. Albano, G. V.; Aureli, R.; Iapalucci, M. C.; Laschi, F.; Longoni, G.; Monari, M.; Zanello, P. J. Chem. Soc., Chem. Commun. 1993, 1501.
26. Longoni, G.; Manassero, M.; Sansoni, M. J. Am. Chem. Soc. 1980, 102, 3242.
27. Albano, G. V.; Azzaroni, F.; lapalucci, M. C.; Longoni, G.; Monari, M.; Mulley, S.; Proserpio, D. M.; Sironi, A. Inorg. Chem. 1994, 33, 5320.
28. Ernst, R. D.; Marks, T. J.; Ibers, J. A. J. Am. Chem. Soc. 1977, 99, 2090.
29. Battiston, G. A.; Bor, G.; Dietler, U.K.; Kettle, S. F. A.; Rossetti, R. ; Sbrignadello, G.; Stanghellini, P. L. Inorg. Chem. 1980, 19, 1961.
30. Churchill, M. R.; DeBoer, B. G. Inorg. Chem. 1977, 16, 878.
31. Churchill, M. R.; Hollander, F. J.; Hutchinson, J. P. Inorg. Chem. 1977, 16, 2655.
32. Bau, R.; Fontal, B.; Kaesz, A. D.; Churchill, M. R. J. Am. Chem. Soc. 1967, 89, 6374.
33. Doyle, G.; Eriksen, K. A.; Van Engen, D. J. Am. Chem. Soc. 1986, 108, 445.
34. We define the molecular axes as X, Y, and Z and the local axes of a CO group as x, y, and z.
35. Kettle, S. F. A.; Paul, I.; Stamper, P. J. Chem. Soc., Dalton Trans. 1972, 2413. Kettle, S. F. A.; Paul, I.; Stamper, P. Inorg. Chim. Acta 1973, 7, 11. Kettle, S. F. A.; Luknar, N. J. Chem. Phys. 1978, 68, 2264.
36. Kettle, S. F. A.; Paul, I.; Stamper, P. J. Chem. Soc., Dalton Trans. 1972, 2413. Kettle, S. F. A.; Paul, I.; Stamper, P. Inorg. Chim. Acta 1973, 7, 11. Kettle, S. F. A.; Luknar, N. J. Chem. Phys. 1978, 68, 2264.
37. Kettle, S. F. A.; Paul, I.; Stamper, P. J. Chem. Soc., Dalton Trans. 1972, 2413. Kettle, S. F. A.; Paul, I.; Stamper, P. Inorg. Chim. Acta 1973, 7, 11. Kettle, S. F. A.; Luknar, N. J. Chem. Phys. 1978, 68, 2264.
38. In the same way, mixing of s- and p-orbitals to give two sp hybrids involves the resultant function energies coming together.
39. Shigeishi, R. A.; King, D. A. Surf. Sci. 1976, 58, 379. Nichols, H.; Hexter, R. M. J. Chem. Phys. 1980, 73, 965.
40. Shigeishi, R. A.; King, D. A. Surf. Sci. 1976, 58, 379. Nichols, H.; Hexter, R. M. J. Chem. Phys. 1980, 73, 965.
41. Battiston, G. A.; Sbrignadello, G.; Bor, G. Inorg. Chem. 1980, 19, 1973.
42. 12 by introducing that which they called "an induced dipole moment". This may immediately be identified as equivalent to the image dipole moment of the SHM.
43. Kettle, S. F. A.; Paul, I. Adv. Organomet. Chem. 1972, 10, 199 and references therein.
44. The Ru/Os distinction has no great effect on the appearance of the spectra of the mixed species,16 a strong indication that the SHM should be relevant.
45. 4h.
46. Albert, K.; Neyman, K. M.; Pacchioni, G.; Rösch, N. Inorg. Chem. 1996, 35, 7370.