CsOH-promoted epoxide ring-opening with phosphines: Mild and efficient synthesis of monohydroxyphosphines

Tetrahedron Letters

Volumn 44, Issue 41, 2003, Pages 7579-7582

  Fox, Daniel L ^a   Robinson, Ashlee A ^a   Frank, James B ^a   Salvatore, Ralph Nicholas ^a  

^a WESTERN KENTUCKY UNIVERSITY   (United States)

Author keywords

Bidentate ligands; Cesium hydroxide; Epoxides; Monohydroxyphosphine; Phosphines

Indexed keywords

CESIUM; EPOXIDE; PHOSPHINE DERIVATIVE;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; INFRARED SPECTROSCOPY; MOLECULAR BIOLOGY; PHOSPHORUS NUCLEAR MAGNETIC RESONANCE; PROTON NUCLEAR MAGNETIC RESONANCE; RING OPENING; ROOM TEMPERATURE; STEREOCHEMISTRY; SYNTHESIS;

EID: 0141629391     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2003.08.068     Document Type: Article

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37. 31P NMR, GC/MS and IR spectra were taken and compared with the known compounds. Elemental analyses were obtained by the Materials Characterization Center at WKU. The stereochemistry of the products have been assigned trans configuration by comparison with the known compounds. See Ref. 9a.