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Volumn 44, Issue 44, 2003, Pages 8051-8055

Diastereoselective allylations and crotylations under phase-transfer conditions using trifluoroborate salts: An application to the total synthesis of (-)-tetrahydrolipstatin

Author keywords

Allylboration; Allyltrifluoroborates; Biphasic; Boron; Phase transfer catalyst; Tetrahydrolipstatin; Total synthesis

Indexed keywords

ALCOHOL DERIVATIVE; ALDEHYDE DERIVATIVE; ALKYL GROUP; ANTIOBESITY AGENT; BORIC ACID; POTASSIUM; SODIUM CHLORIDE; TETRAHYDROLIPSTATIN; TRIFLUOROBORATE; UNCLASSIFIED DRUG;

EID: 0141571033     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2003.09.053     Document Type: Article
Times cited : (81)

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    • Hanessian's approach (see Ref. 16h) generated a mixture of 1,2-syn-2,4-anti, 1,2-anti-2,4-anti, 1,2-syn-2,4-syn products in a 1: 1.5: 0.12 ratio, (the major products have an anti-2,4 relationship due to chelation controlled addition).
    • Hanessian's approach (see Ref. 16h) generated a mixture of 1,2-syn-2,4-anti, 1,2-anti-2,4-anti, 1,2-syn-2,4-syn products in a 1: 1.5: 0.12 ratio, (the major products have an anti-2,4 relationship due to chelation controlled addition).


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