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Volumn 111, Issue 2, 1999, Pages 737-749

Transient nucleation in oxide glasses: The effect of interface dynamics and subcritical cluster population

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EID: 0043226735     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.479353     Document Type: Article
Times cited : (17)

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    • note
    • When quenching the liquid, a structure freezes in that relaxes to a lower free energy state provided that the mobility of the molecules is high enough. Accordingly, the free energy of the glass/crystal interface depends on the heat treatment. At high temperatures where γ(T) is approximately linear, the relaxation is fast and the true γ(T) can be observed. However, the relaxation time increases steeply as the temperature decreases. Thus at low temperatures the steady-state nucleation occurs in the unrelaxed glass (structure frozen in at a higher temperature), i.e., the respective y is higher than for the relaxed state. Consequently, in a temperature range below the glass transition (occurring during quenching), nucleation takes place in differently relaxed states that span from the fully relaxed state at high temperatures to the unrelaxed state at low temperatures, a phenomenon that explains the minimum in the interfacial free energy shown in Fig. 8. However, considering the short structural relaxation times of glass (Ref. 44), this mechanism is likely to occur only if the structural relaxation in the glass/crystal boundary layer is considerably slower than in the bulk glass.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.