Fe3+-exchanged fluorotetrasilicic mica as an active and reusable catalyst for Michael reaction

Tetrahedron Letters

Volumn 44, Issue 40, 2003, Pages 7421-7424

  Shimizu, Ken Ichi ^a   Miyagi, Masato ^a   Kan no, Toshiki ^a   Kodama, Tatsuya ^a   Kitayama, Yoshie ^a  

^a NIIGATA UNIVERSITY   (Japan)

Author keywords

Fe3+ exchanged clay; Fluorotetrasilicic mica; Michael reaction

Indexed keywords

ESTER DERIVATIVE; FERRIC ION; KETONE DERIVATIVE; MICA; VINYL DERIVATIVE;

ARTICLE; CATALYSIS; CATALYST; GAS CHROMATOGRAPHY; IMMOBILIZATION; MICHAEL ADDITION; PROTON NUCLEAR MAGNETIC RESONANCE; THIN LAYER CHROMATOGRAPHY;

MICA;

EID: 0042836600     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2003.08.048     Document Type: Article

References (20)

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16. 3 and Fe-NaY are 2.3, 1.6, 1.4, 6.1, 4.8 and 2.1 wt%, respectively.
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18. Progress of the reaction was monitored by GC analysis of aliquots using n-dodecane as internal standard.
19. 2O using smaller amount of the catalyst (0.1 mol%).
20. 3+ in the interlayer is available as a catalyst for the reaction.