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85034286495
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note
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The observed deuterium effect on the proton-transfer time (1.6 ps/ 1.1 ps = 1.5) is smaller than is expected for reactions by quantum mechanical tunneling. It suggests that tunneling is not the major mechanism for the proton transfer of the 7-azaindole dimer in solution at room temperature.
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30
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0001357854
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85034275234
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note
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This radiative lifetime of the monomer is obtained by integration of the lowest-energy band of the monomeric absorption spectrum from 235 to 315 nm.
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32
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85034299099
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note
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In this literature, the quantum yield of the tautomeric fluorescence is written as 0.002. However, judging from their argument using the value, 0.002 is probably a misprint and the "real" value must be 0.02.
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33
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0031237219
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85034291651
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note
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This radiative lifetime of 140 ns may be a shorter limit because the lowest-energy absorption band of 7-methyl-7H-pyrrolo[2,3-e]pyridine significantly overlaps with strong higher-energy absorption bands.
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37
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85034303574
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note
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Uncertainty in the evaluated oscillator strength values is estimated as around 30%. It comes predominantly from uncertainties in the quantum yield of the tautomer fluorescence and those in the fitting analysis of the fluorescence spectra using the Lorentzian functions.
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38
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85034285938
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note
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r4 = 7.5 ns is obtained. The fluorescence quantum yield of the monomeric excited state corresponding to this radiative lifetime is φ4 = 1.02/7.5 = 0.136.
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41
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0000352971
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Rich, R. L.; Chen, Y.; Neven, D.; Negrerie, M.; Gai, F.; Petrich, J. W. J. Phys. Chem. 1993, 97, 1781.
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85034281352
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To be submitted
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Quantitative analysis of the fluorescence anisotropy change of the 7-azaindole dimer will be given elsewhere. Takeuchi, S.; Tahara, T. To be submitted.
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Takeuchi, S.1
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