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85033134813
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Particle dimensions (221 particles sized): 10.7 nm ± 1.3 nm (long axis); 9.4 nm ± 1.1 nm (short axis)
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Particle dimensions (221 particles sized): 10.7 nm ± 1.3 nm (long axis); 9.4 nm ± 1.1 nm (short axis).
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26
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85033150306
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in press
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85033138451
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note
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Optical spectra were acquired using a Varian Cary 5 spectrophotometer; particle coverages were calculated by atomic absorption measurements (Perkin-Elmer 1100B outfitted with a graphite furnace) on 50% aqueous aqua regia-digested surfaces, assuming all Au particles were prolate spheroids, with 10.7 × 10.7 × 9.4 nm axes.
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29
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37049108231
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32
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85033133394
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note
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14
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33
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85033149676
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note
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14b data showing the presence of connective paths over large areas after 5-6 exposures to Au. If there were direct particle contact, these samples would conduct, contrary to what is observed.
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35
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0041835165
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Edwards, P. P.; Rao, C. N. R., Eds.; Taylor and Francis: London, and references therein
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36
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85033135361
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note
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14 The film volume (v) is defined as the product of the cross-sectional area (a, which is constant) and the film thickness (z). If the number of Au treatments is n and z = yn (where y is a constant), then v = ayn. The volume fraction f is defined as the ratio of the Au volume (g) to v. Since g = qθa, where q is the volume per particle (a constant), θ = the number of particles/cross-sectional area, and a is defined as above, and θ = rn (where r is a constant, Supporting Information), then f = g/v = (qrn)/(ayn) = a constant. Thus, we conclude that f remains roughly constant. An upper limit of f ≈ 0.5 can be obtained by integration of light areas in a FE-SEM image and assuming that the volume under each integrated element is completely filled with Au.
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37
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0000285027
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