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This may also happen due to geometric reason. For a bis-chelating bidentate ligand, forming two five-member chelate rings, the M-N bond length for the middle nitrogen is smaller than those for the terminal nitrogens.
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note
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Neglect of the interdimer exchange interaction in the above approach is justified by the weakness of that interaction. Thus, between 1.8 and 5 K, the susceptibility follows the Curie-Weiss law, χ = C/(T - θ), with C = 4.2 K emu/mol and θ ≈ -2 K. The interdimer exchange integral is then estimated as zJ′ = 0/4 -0.5 K, z being the number of nearest neighbors. On the other hand, D < 0. hence the ground state of the dimer is a nonmagnetic singlet, therefore the presence of the small interdimer interaction, z|J′| ≪ |D|, is irrelevant. Any possibility of a positive zero-field splitting can be ruled out, since this would have meant a doublet ground state and a Curie-Weiss behavior with a much smaller Curie constant. C = 2.3 K emu/mol. This conclusion holds regardless of the interdimer interaction, which affects θ but not C.
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