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Volumn 681, Issue 1-2, 2003, Pages 12-23

Transition metal-catalyzed polymerization of 1,3,5-trioxane

Author keywords

Formaldehyde; Homogeneous catalysis; Molybdenum; Polyoxymethylene; Trioxane; X ray structures

Indexed keywords

1,2,4 TRIOXANE DERIVATIVE; ALKENE DERIVATIVE; CARBON 13; CATION; FORMALDEHYDE; FORMIC ACID DERIVATIVE; LEWIS ACID; MOLYBDENUM COMPLEX; OXEPANE DERIVATIVE; PROTON; SODIUM CARBONATE; TRANSITION ELEMENT; WATER;

EID: 0042389436     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-328X(03)00527-8     Document Type: Article
Times cited : (8)

References (59)
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    • It may be anticipated that the triflate anion participates in the process, e.g. intermediate formation of esters with the cationic chain end and thereby stabilizing the chain end into a dormant species
    • It may be anticipated that the triflate anion participates in the process, e.g. intermediate formation of esters with the cationic chain end and thereby stabilizing the chain end into a dormant species.
  • 47
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    • 2 will immediately boil off at 80°C, but it served for a constant amount of catalyst in every run
    • 2 will immediately boil off at 80°C, but it served for a constant amount of catalyst in every run
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    • Due to the elimination of gaseous formaldehyde during the combustion process, the found carbon values are somewhat lower
    • Due to the elimination of gaseous formaldehyde during the combustion process, the found carbon values are somewhat lower
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    • 1H-NMR data of 6 were compared to those of an authentic sample
    • 1H-NMR data of 6 were compared to those of an authentic sample
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    • shelxs-86 Göttingen, Germany: University of Göttingen
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.