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note
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It should be noted that compounds A, B, and C were obtained in a reduced state, because an excess amount of aniline worked as a reductant and their yields were dependent on their reductive efficiency to the products.
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0042052073
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note
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4 cross-coupling conditions. The cross coupling of PDA with a thiophene group was performed using a Stille coupling agent without CuI. The PDA unit would be oxidized in the palladium-catalyzed cycle, but model compounds of the polymers, 2,5-diphenyl- (1a) or 2,5-dithienyl- (1b) PDAs, were obtained in a reduced state through palladium-catalyzed Suzuki coupling or cross coupl ing of A with benzeneboronic acid or 2-(tributylstannyl)-thiophene in yields of 87% and 92%, respectively.
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