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Volumn 36, Issue 17, 2003, Pages 6325-6332

π-Conjugated polymers exhibiting a novel doping based on redox of side chains

Author keywords

[No Author keywords available]

Indexed keywords

POLYPHENYLENE; POLYTHIOPHENE; RADICAL CATION; SUZUKI COUPLING;

EID: 0042320828     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma025833j     Document Type: Article
Times cited : (14)

References (27)
  • 22
    • 0043053804 scopus 로고    scopus 로고
    • note
    • It should be noted that compounds A, B, and C were obtained in a reduced state, because an excess amount of aniline worked as a reductant and their yields were dependent on their reductive efficiency to the products.
  • 23
    • 0042052073 scopus 로고    scopus 로고
    • note
    • 4 cross-coupling conditions. The cross coupling of PDA with a thiophene group was performed using a Stille coupling agent without CuI. The PDA unit would be oxidized in the palladium-catalyzed cycle, but model compounds of the polymers, 2,5-diphenyl- (1a) or 2,5-dithienyl- (1b) PDAs, were obtained in a reduced state through palladium-catalyzed Suzuki coupling or cross coupl ing of A with benzeneboronic acid or 2-(tributylstannyl)-thiophene in yields of 87% and 92%, respectively.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.