Intramolecular sensitization within steroids: Excited-state interaction of C-17 α and β carbon-bromine bonds with a C-6 carbonyl group

Canadian Journal of Chemistry

Volumn 81, Issue 6, 2003, Pages 660-668

  Li, Wen Shan ^a,b   Torun, Lokman ^a   Morrison, Harry ^a  

^a PURDUE UNIVERSITY   (United States)

^b INSTITUTE OF CHEMISTRY   (Taiwan)

Author keywords

Bromosteroid; Intramolecular singlet singlet energy transfer (ISSET); Ketosteroid; Photodehalogenation

Indexed keywords

CHEMICAL BONDS; CHROMOPHORES; ELECTRON ENERGY LEVELS; FURAN RESINS; ISOMERS; KETONES; MOLECULAR STRUCTURE; PHOTOCHEMICAL REACTIONS; SYNTHESIS (CHEMICAL);

PHOTOSENSITIZATION REACTIONS; STEROIDS;

BROMINE COMPOUNDS;

17ALPHA BROMO 3ALPHA (TRIPHENYLSILYLOXY) 5ALPHA ANDROSTAN 6 ONE; 17BETA BROMO 3BETA (TRIPHENYLSILYLOXY) 5ALPHA ANDROSTAN 6 ONE; BROMINE; CARBON; CARBONYL DERIVATIVE; KETONE; OXOSTEROID; STEROID; TETRAHYDROFURAN; UNCLASSIFIED DRUG;

AQUEOUS SOLUTION; ARTICLE; CHEMICAL BOND; DEHALOGENATION; ENERGY TRANSFER; ISOMER; MOLECULAR INTERACTION; PHOTOCHEMISTRY; PHYSICS; SYNTHESIS;

EID: 0042233634     PISSN: 00084042     EISSN: None     Source Type: Journal    
DOI: 10.1139/v03-055     Document Type: Article

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