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It has been documented that photolysis of N,N,N′,N′-tetramethyl-benzidine in degassed acetonitrile leads to absorptions due to the triplet state and the cation of this compound. For A-S-B, we used a nonpolar solvent (cyclohexane) and only observed the absorption of the triplet state. Indeed in acetonitrile cation absorption was detected. Analysis of the cation absorption in acetonitrile as a function of laser intensity reveals that the cation is formed via monophotonic excitation of A-S-B to its singlet excited state followed by spontaneous ejection of an electron.
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