Hydroboration of bis(trimethylsilylethynyl)silanes with 9-borabicyclo[3.3.1]nonane. A new route to 1-sila-3-cyclopentenes and to a 1-sila-2,4-cyclopentadiene

Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences

Volumn 58, Issue 6, 2003, Pages 543-552

  Wrackmeyer, Bernd ^a   Maisel, Heidi E ^a   Milius, Wolfgang ^a   Bhatti, Moazzam H ^a,b   Ali, Saqib ^a,b  

^a UNIVERSITY OF BAYREUTH   (Germany)

^b QUAID I AZAM UNIVERSITY   (Pakistan)

Author keywords

Alkynes; Hydroboration; Isomerisation; NMR; Silole

Indexed keywords

ISOMERS; MOLAR RATIO; NUCLEAR MAGNETIC RESONANCE; SILANES;

ALKYNES; CYCLOPENTADIENES; CYCLOPENTENES; HYDROBORATION; ISOMERISATION; SILOLE; TRIMETHYLSILYL; X RAY STRUCTURAL ANALYSIS;

SILICON;

1 SILA 2,4 CYCLOPENTADIENE; 9 BORABICYCLO[3.3.1]NONANE; BICYCLO COMPOUND; BORANE DERIVATIVE; CYCLOPENTADIENE DERIVATIVE; CYCLOPENTENE DERIVATIVE; HETEROCYCLIC COMPOUND; ISOBUTYLENE; SILANE DERIVATIVE; TOLUENE; UNCLASSIFIED DRUG;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CHEMICAL BOND; CRYSTAL STRUCTURE; HYDROBORATION; ISOMER; NUCLEAR MAGNETIC RESONANCE; PROTON NUCLEAR MAGNETIC RESONANCE; X RAY CRYSTALLOGRAPHY;

EID: 0041765707     PISSN: 09320776     EISSN: None     Source Type: Journal    
DOI: 10.1515/znb-2003-0610     Document Type: Article

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58. Crystallographic data (excluding structure factors) for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-205243 (2a), and CCDC-205244 (2b). Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB2 1EZ, UK [fax (internat.): +44(0)1223/336033; e-mail: deposit@ccdc.cam.ac.uk].