Basic interactions of water with organic compounds

Journal of Physical Chemistry B

Volumn 107, Issue 31, 2003, Pages 7976-7980

  Iwamoto, Reikichi ^a   Matsuda, Toshihiko ^a   Sasaki, Tatsuyoshi ^a   Kusanagi, Hiroshi ^b  

^a Kansai Research Institute ^*  (Japan)

^b NATIONAL FISHERIES UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

HYDROGEN BONDS; HYDROPHOBICITY; INFRARED SPECTROSCOPY; WATER;

ORGANIC MOLECULES;

ORGANIC COMPOUNDS;

EID: 0041732193     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp030561n     Document Type: Article

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28. -1 band of the water, the molar absorptivity of which can be determined from the observed spectrum at the concentration 5% (v/v), where the water is essentially completely "one-bonded", could be used to estimate the population of the species of the "one-bonded" water at a concentration, and then the population of the "two-bonded" water could be determined by subtraction of that from the solubility at the concentration. This was not, however, possible for the following reasons: First, the measured intensity at 5% (v/v), which is so weak, did not have sufficient accuracy for the estimation. Second, it was not possible to completely remove the contamination of humidity in air into the solution of P during the experimental procedure in the present experiment. The contamination seriously affects the reliability of the intensity of the weak absorption of the water dissolved, which is obtained by subtracting the spectrum of the P solution.