Synthesis, structure, bridge - Terminal exchange kinetics, and molecular orbital calculations of pyrazolate-bridged digallium complexes containing bridging phenyl groups

Journal of the American Chemical Society

Volumn 125, Issue 37, 2003, Pages 11152-11153

  Sirimanne, Chatu T ^a   Knox, John E ^a   Heeg, Mary Jane ^a   Schlegel, H Bernhard ^a   Winter, Charles H ^a  

^a WAYNE STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

GALLIUM; PHENYL GROUP; PYRAZOLE DERIVATIVE;

ARTICLE; CALCULATION; CARBON NUCLEAR MAGNETIC RESONANCE; CHEMICAL BOND; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; HYDROGEN BOND; MOLECULAR MODEL; MOLECULAR STABILITY; SOLID STATE; STEREOSPECIFICITY; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

EID: 0041692325     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja036256x     Document Type: Article

References (26)

1. Selected recent leading references: (a) McGrady, G. S.; Turner, J. F. C. ; Ibberson, R. M.; Prager, M. Organometallics 2000, 19, 4398. (b) Son, A. J. R. ; Thom, M. G.; Fanwick, P. E.; Rothwell, I. P. Organometallics 2003, 22, 2318. (c) Yu, Z. K.; Heeg, M. J.; Winter, C. H. Chem. Commun. 2001, 122, 353. (d) Yu, Z. K.; Wittbrodt, J. M.; Heeg, M. J.; Schlegel, H. B.; Winter, C. H. J. Am. Chem. Soc. 2000, 122, 9338.
2. Selected recent leading references: (a) McGrady, G. S.; Turner, J. F. C. ; Ibberson, R. M.; Prager, M. Organometallics 2000, 19, 4398. (b) Son, A. J. R. ; Thom, M. G.; Fanwick, P. E.; Rothwell, I. P. Organometallics 2003, 22, 2318. (c) Yu, Z. K.; Heeg, M. J.; Winter, C. H. Chem. Commun. 2001, 122, 353. (d) Yu, Z. K.; Wittbrodt, J. M.; Heeg, M. J.; Schlegel, H. B.; Winter, C. H. J. Am. Chem. Soc. 2000, 122, 9338.
3. Selected recent leading references: (a) McGrady, G. S.; Turner, J. F. C. ; Ibberson, R. M.; Prager, M. Organometallics 2000, 19, 4398. (b) Son, A. J. R. ; Thom, M. G.; Fanwick, P. E.; Rothwell, I. P. Organometallics 2003, 22, 2318. (c) Yu, Z. K.; Heeg, M. J.; Winter, C. H. Chem. Commun. 2001, 122, 353. (d) Yu, Z. K.; Wittbrodt, J. M.; Heeg, M. J.; Schlegel, H. B.; Winter, C. H. J. Am. Chem. Soc. 2000, 122, 9338.
4. Selected recent leading references: (a) McGrady, G. S.; Turner, J. F. C. ; Ibberson, R. M.; Prager, M. Organometallics 2000, 19, 4398. (b) Son, A. J. R. ; Thom, M. G.; Fanwick, P. E.; Rothwell, I. P. Organometallics 2003, 22, 2318. (c) Yu, Z. K.; Heeg, M. J.; Winter, C. H. Chem. Commun. 2001, 122, 353. (d) Yu, Z. K.; Wittbrodt, J. M.; Heeg, M. J.; Schlegel, H. B.; Winter, C. H. J. Am. Chem. Soc. 2000, 122, 9338.
5. (a) Malone, J. F.; McDonald, W. S. J. Chem. Soc., Dalton Trans. 1972, 2646. (b) Malone, J. F.; McDonald, W. S. J. Chem. Soc., Dalton Trans. 1972, 2649. (c) Brauer, D. J.; Kruger, C. Z. Naturforsch. 1979, 34B, 1293.
6. (a) Malone, J. F.; McDonald, W. S. J. Chem. Soc., Dalton Trans. 1972, 2646. (b) Malone, J. F.; McDonald, W. S. J. Chem. Soc., Dalton Trans. 1972, 2649. (c) Brauer, D. J.; Kruger, C. Z. Naturforsch. 1979, 34B, 1293.
7. (a) Malone, J. F.; McDonald, W. S. J. Chem. Soc., Dalton Trans. 1972, 2646. (b) Malone, J. F.; McDonald, W. S. J. Chem. Soc., Dalton Trans. 1972, 2649. (c) Brauer, D. J.; Kruger, C. Z. Naturforsch. 1979, 34B, 1293.
8. Erker, G.; Albrecht, M.; Krüger, C.; Nolte, M.; Werner, S. Organometallics 1993, 12, 4979. Albright, M. J.; Butler, W. M.; Anderson, T. J. ; Glick, M. D.; Oliver, J. P. J. Am. Chem. Soc. 1976, 98, 3995. Stucky, G. D.; McPherson, A. M.; Rhine, W. E.; Eisch, J. J.; Considine, J. L. J. Am. Chem. Soc. 1974, 96, 1941.
9. Erker, G.; Albrecht, M.; Krüger, C.; Nolte, M.; Werner, S. Organometallics 1993, 12, 4979. Albright, M. J.; Butler, W. M.; Anderson, T. J. ; Glick, M. D.; Oliver, J. P. J. Am. Chem. Soc. 1976, 98, 3995. Stucky, G. D.; McPherson, A. M.; Rhine, W. E.; Eisch, J. J.; Considine, J. L. J. Am. Chem. Soc. 1974, 96, 1941.
10. Erker, G.; Albrecht, M.; Krüger, C.; Nolte, M.; Werner, S. Organometallics 1993, 12, 4979. Albright, M. J.; Butler, W. M.; Anderson, T. J. ; Glick, M. D.; Oliver, J. P. J. Am. Chem. Soc. 1976, 98, 3995. Stucky, G. D.; McPherson, A. M.; Rhine, W. E.; Eisch, J. J.; Considine, J. L. J. Am. Chem. Soc. 1974, 96, 1941.
11. CpIn(I) complexes contain bridging cyclopentadienyl ligands; for leading references, see: Schumann, H.; Kucht, H.; Kucht, A.; Görlitz, F. H.; Dietrich, A. Z. Naturforsch. 1992, 47B, 1241. Beachley, O. T., Jr.; Lees, J. F. ; Rogers, R. D. J. Organomet. Chem. 1991, 418, 165. Beachley, O. T., Jr.; Pazik, J. C.; Glassman, T. E.; Churchill, M. R.; Fettinger, J. C.; Blom, R. Organometallics 1988, 7, 1051.
12. CpIn(I) complexes contain bridging cyclopentadienyl ligands; for leading references, see: Schumann, H.; Kucht, H.; Kucht, A.; Görlitz, F. H.; Dietrich, A. Z. Naturforsch. 1992, 47B, 1241. Beachley, O. T., Jr.; Lees, J. F. ; Rogers, R. D. J. Organomet. Chem. 1991, 418, 165. Beachley, O. T., Jr.; Pazik, J. C.; Glassman, T. E.; Churchill, M. R.; Fettinger, J. C.; Blom, R. Organometallics 1988, 7, 1051.
13. CpIn(I) complexes contain bridging cyclopentadienyl ligands; for leading references, see: Schumann, H.; Kucht, H.; Kucht, A.; Görlitz, F. H.; Dietrich, A. Z. Naturforsch. 1992, 47B, 1241. Beachley, O. T., Jr.; Lees, J. F. ; Rogers, R. D. J. Organomet. Chem. 1991, 418, 165. Beachley, O. T., Jr.; Pazik, J. C.; Glassman, T. E.; Churchill, M. R.; Fettinger, J. C.; Blom, R. Organometallics 1988, 7, 1051.
14. (a) Tecle, B.; Ilsley, W. H.; Oliver, J. P. Inorg. Chem. 1981, 20, 2335. (b) Lee, B.; Pennington, W. T.; Laske, J. A.; Robinson, G. H. Organometallics 1990, 9, 2864. (c) Cowley, A. H.; Brown, D. S.; Decken, A.; Kamepalli, S. Chem. Commun. 1996, 2425.
15. (a) Tecle, B.; Ilsley, W. H.; Oliver, J. P. Inorg. Chem. 1981, 20, 2335. (b) Lee, B.; Pennington, W. T.; Laske, J. A.; Robinson, G. H. Organometallics 1990, 9, 2864. (c) Cowley, A. H.; Brown, D. S.; Decken, A.; Kamepalli, S. Chem. Commun. 1996, 2425.
16. (a) Tecle, B.; Ilsley, W. H.; Oliver, J. P. Inorg. Chem. 1981, 20, 2335. (b) Lee, B.; Pennington, W. T.; Laske, J. A.; Robinson, G. H. Organometallics 1990, 9, 2864. (c) Cowley, A. H.; Brown, D. S.; Decken, A.; Kamepalli, S. Chem. Commun. 1996, 2425.
17. Rahbarnoohi, H.; Kumar, R.; Heeg, M. J.; Oliver, J. P. Organometallics 1994, 13, 3300.
18. Malone, J. F.; McDonald, W. S. J. Chem. Soc. 1970, 3362.
19. Mitzel, N. W.; Lustig, C.; Berger, R. J. F.; Runeberg, N. Angew. Chem., Int. Ed. 2002, 41, 2519. Boese, R.; Downs, A. J.; Greene, T. M.; Hall, A. W.; Morrison, C. A.; Parsons, S. Organometallics 2003, 22, 2450.
20. Mitzel, N. W.; Lustig, C.; Berger, R. J. F.; Runeberg, N. Angew. Chem., Int. Ed. 2002, 41, 2519. Boese, R.; Downs, A. J.; Greene, T. M.; Hall, A. W.; Morrison, C. A.; Parsons, S. Organometallics 2003, 22, 2450.
21. Spectral, analytical, and kinetics data for 1-3 and positional parameters for 4 and 5 are contained in the Supporting Information.
22. Frisch, M. J.; et al. Gaussian 01, Development Version (Revision B.03+); Gaussian, Inc.: Pittsburgh, PA, 2002.
23. Becke, A. D. Phys. Rev. A: At., Mol., Opt. Phys. 1988, 38, 3098. Lee, C. T.; Yang, W. T.; Parr, R. G. Phys. Rev. B: Condens. Matter 1988, 37, 785. Becke, A. D. J. Chem. Phys. 1993, 98, 5648.
24. Becke, A. D. Phys. Rev. A: At., Mol., Opt. Phys. 1988, 38, 3098. Lee, C. T.; Yang, W. T.; Parr, R. G. Phys. Rev. B: Condens. Matter 1988, 37, 785. Becke, A. D. J. Chem. Phys. 1993, 98, 5648.
25. Becke, A. D. Phys. Rev. A: At., Mol., Opt. Phys. 1988, 38, 3098. Lee, C. T.; Yang, W. T.; Parr, R. G. Phys. Rev. B: Condens. Matter 1988, 37, 785. Becke, A. D. J. Chem. Phys. 1993, 98, 5648.
26. Sirimanne, C.; Heeg, M. J.; Winter, C. H. unpublished results.