Oxidative stability of structured lipids produced from sunflower oil and caprylic acid

European Journal of Lipid Science and Technology

Volumn 105, Issue 8, 2003, Pages 436-448

  Timm Heinrich, Maike ^a   Xu, Xuebing ^a   Nielsen, Nina Skall ^a   Jacobsen, Charlotte ^a  

^a TECHNICAL UNIVERSITY OF DENMARK   (Denmark)

Author keywords

Antioxidants; Oxidative stability; Sensory assessment; Structured lipids

Indexed keywords

ANTIOXIDANT; ASCORBYL PALMITATE; CITRIC ACID; GALLIC ACID; GRINDOX 117; LIPID; OCTANOIC ACID; SUNFLOWER OIL; TOCOPHEROL; UNCLASSIFIED DRUG;

ANTIOXIDANT ACTIVITY; ARTICLE; CHEMICAL STRUCTURE; LIPOGENESIS; MOLECULAR STABILITY; OXIDATION; PURIFICATION; STORAGE;

HELIANTHUS;

EID: 0041629646     PISSN: 14387697     EISSN: None     Source Type: Journal    
DOI: 10.1002/ejlt.200300794     Document Type: Article

References (27)

1. K.-T Lee, C. C. Akoh: Structured lipids: synthesis and applications. Food Rev. Int. 14 (1998) 17-34.
2. V. Sharma, S. Arora, B. K. Wadhwa: Structured lipids and their applications. Indian Food Ind. 20 (2001) 52-55.
3. R. J. Jandacek, J. A. Whiteside, B. N. Holcombe, R. A. Volpenheim, J. D. Taulbee: The rapid hydrolysis and efficient absorption of triglycerides with octanoic acid in the 1 and 3 positions and long-chain fatty acid in the 2 position. Am. J. Clin. Nutr. 45 (1987) 940-945.
4. J. Stein: Chemically defined structured lipids: current status and future directions in gastrointestinal diseases. Int. J. Colorect. Dis. 14 (1999) 79-85.
5. W. L. Porter: Paradoxical behavior of antioxidants in food and biological systems. Toxicol. Ind. Health 9 (1993) 93-122.
6. C. Jacobsen, K. Hartvigsen, P. Lund, A. S. Meyer, J. Adler-Nissen, J. Holstborg, G. Hølmer: Oxidation in fish-oil-enriched mayonnaise: 1. Assessment of propyl gallate as an antioxidant by discriminant partial least squares regression analysis. Eur. Food Res. Technol. 210 (1999) 13-30.
7. X. Xu, S. Balchen, C.-E. Høy, J. Adler-Nissen: Production of specific-structured lipids by enzymatic interesterification in a pilot continuous enzyme bed reactor. J. Am. Oil Chem. Soc. 75 (1998) 1573-1579.
8. X. Xu, C. Jacobsen, N. S. Nielsen, M. Timm-Heinrich, D. Zhou: Purification and deodorization of structured lipids by short path distillation. Eur. J. Lipid Sci. Technol. 104 (2002) 745-755.
9. C. C. Becker, A. Rosenquist, G. Hølmer: Regiospecific analysis of triacylglycerols using allyl magnesium bromide. Lipids 28 (1993) 147-149.
10. H. Mu, P. Kalo, X. Xu, C.-E. Høy: Chromatographic methods in the monitoring of lipase-catalyzed interesterification. Eur. J. Lipid Sci. Technol. 102 (2000) 202-211.
11. H. Mu, H. Sillen, C.-E. Høy: Identification of diacylglycerols and triacylglycerols in a structured lipid sample by atmospheric pressure chemical ionisation liquid chromatography/mass spectrometry. J. Am. Oil Chem. Soc. 77 (2000) 1049-1059.
12. Official method Ce 8-89: Determination of tocopherols and tocotrienols in vegetable oils and fats by HPLC. AOCS Official Methods and Recommended Practices. 5. ed. A.O.C.S. Champaign, IL. (USA) 1998.
13. Official method Ca 5a-40: Free fatty acids. AOCS Official Methods and Recommended Practices. 5. ed. A.O.C.S., Champaign, IL., USA, 1998.
14. N. C. Shantha, E. A. Decker: A rapid, sensitive, iron-based spectrophotometric method for determination of peroxide values of food lipids. J. AOAC Int. 77 (1994) 421-424.
15. K. Rørbæk, B. Jensen: Optimizing headspace sampling temperature and time for analysis of volatile oxidation products in fish oil. J. Am. Oil Chem. Soc. 74 (1997) 1607-1609.
16. M. Martens, H. Martens: Partial least squares regression. In: Statistical procedures. Ed. J. R. Piggott, Elsevier, London (Great Britain) 1986, pp. 293-359.
17. E. N. Frankel, W. E. Neff, E. Selke: Analysis of autoxidized fats by gas chromatography-mass spectrometry: VII. Volatile thermal decomposition products of pure hydroperoxides from autoxidized and photosensitized oxidized methyl oleate, linoleate and linolenate. Lipids 16 (1981) 279-285.
18. E. N. Frankel: Review: Recent advantages in lipid oxidation. J. Sci. Food Agric. 54 (1991) 495-511.
19. H. T. Badings: Cold-storage defects in butter and their relation to the autoxidation of unsaturated fatty acids. Neth. Milk Dairy J. 23/24 (1970) 146-259.
20. C. Karahadian, R. C. Lindsay: Evaluation of compounds contributing to characterizing fishy flavors in fish oils. J. Am. Oil Chem. Soc. 66 (1989) 953-960.
21. S. Wada, C. Koizumi: Influence of the position of unsaturated fatty acid esterified glycerol on the oxidation rate of triglyceride. J. Am. Oil Chem. Soc. 60 (1983) 1105-1109.
22. W. E. Neff, M. El-Agaimy: Effect of linoleic acid position in triacylglycerols on their oxidative stability. Lebensm. Wiss. Technol. 29 (1996) 772-775.
23. C. C. Akoh, C. O. Moussata: Characterization and oxidative stability of enzymatically produced fish and canola oil-based structured lipids. J. Am. Oil Chem. Soc. 78 (2001) 25-30.
24. H. Konishi, W. E. Neff, T. L. Mounts: Oxidative stability of soybean products obtained by regioselective chemical interesterification. J. Am. Oil Chem. Soc. 72 (1995) 1393-1398.
25. C. Jacobsen, K. Hartvigsen, M. K. Thomsen, L. F. Hansen, P. Lund, L. H. Skibsted, G. Hølmer, J. Adler-Nissen, A. S. Meyer: Lipid oxidation in fish oil enriched mayonnaise: Calcium disodium ethylenediaminetetraacetate, but not gallic acid, strongly inhibited oxidative deterioration. J. Agric. Food Chem. 49 (2001) 1009-1019.
26. F. A. M. Silva, F. Borges, M. A. Ferreira: Effects of phenolic propyl esters on the oxidative stability of refined sunflower oil. J. Agric. Food Chem. 49 (2001) 3936-3941.
27. C. G. Beddows, C. Jagait, M. J. Kelly: Effect of ascorbyl palmitate on the preservation of α-tocopherol in sunflower oil, alone and with herbs and spices. Food Chem. 73 (2001) 255-261.