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(h) For historical view and definitions of fluorous chemistry, also see: Gladysz, J.; Curran, D. P. Tetrahedron 2002, 58, 3823.
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The aldol reaction of silyl enol ethers using TBAF in the micro reactor by electro osmotic flow (EOF) has been recently reported:
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The aldol reaction of silyl enol ethers using TBAF in the micro reactor by electro osmotic flow (EOF) has been recently reported: Wiles C., Watts P., Haswell S.J., Pombo-Villar E. Lab on a Chip. 2001;100.
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Fundamentals of Microfabrication; Madou, M., Ed.; CRC Press: Boca Raton, 2000 Jaeger, R. C. Modular Series on Solid State Devices; Neudeck, G. W.; Pierret, R. F., Eds.; Addison-Wesley, 1993.
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Koppel and Taft et al. have reported the gas phase acidities of a variety of super acids: Bis(trifluoromethanesulfonyl)amine is stronger than trifluofomethanesulfonic acid by ΔG=7.7 kcal/mol and tris(trifluoromethanesulfonyl)methane is stronger than bis(trifluoromethanesulfonyl)amine by ΔG=2.8 kcal/mol. They have also reported that bis(perfluorobutanesulfonyl)amine is stronger than bis(trifluoromethanesulfonyl)amine by ΔG=7.7 kcal/mol: J. Am. Chem. Soc. 1994, 116, 3047.
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Motoyama, Y.3
Sakaguchi, H.4
Maruta, M.5
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