Hydrolysis of spirophosphoranes with a saturated 1,3,2-dioxaphosphorinane ring: X-ray Structure of the intermolecularly H-bonded phosphate ester (OCH2CMe2CH2O) P(O) (2,2′-O-C6H4-C6H4OH)

Polyhedron

Volumn 17, Issue 20, 1998, Pages 3643-3648

  Swamy, K C Kumara ^a   Said, Musa A ^a   Kumaraswamy, Sudha ^a   Herbst Irmer, R ^b   Pülm, Melanie ^b  

^a UNIVERSITY OF HYDERABAD   (India)

^b UNIVERSITY OF GÖTTINGEN   (Germany)

Author keywords

Hydrogen bonding; Hydrolysis; Phosphorinane; Spirophosphorane; X ray structure

Indexed keywords

EID: 0041193009     PISSN: 02775387     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0277-5387(98)00160-0     Document Type: Article

References (14)

1. McGall, G. H. and McClelland, R. A., Can. J. Chem., 1991, 69, 2064.
2. Gallucci, J. C. and Holmes, R. R., Inorg. Chem., 1980, 19, 3540.
3. Ramirez, F., Nagabhushanam, M. and Smith, C. P., Tetrahedron, 1968, 24, 1785.
4. Said, M. A., Kumara Swamy, K. C., Chandra Mohan, K. and Venkata Lakshmi, N., Tetrahedron, 1994, 50, 6989.
5. Said, M. A., Pülm, M., Herbst-Irmer, R. and Kumara Swamy, K. C., J. Am. Chem. Soc., 1996, 118, 9841.
6. Said, M. A., Pülm, M., Herbst-Irmer, R. and Kumara Swamy, K. C., Inorg. Chem., 1997, 36, 2044.
7. Perrin, D. D., Armarego, W. L. F. and Perrin, D. R., Purification of Laboratory Chemicals. Pergamon, Oxford, 1986.
8. Kottke, T. and Stalke, D., J. Appl. Crystallogr., 1993, 26, 615.
9. Clegg, W., Acta Crystallogr., 1981, A37, 22.
10. Sheldrick, G. M., SHELXS-90, Acta Crystallogr., 1990, A46, 467.
11. Sheldrick, G. M., SHELXL-93. University of Göttingen, 1993.
12. Flack, H. D., Acta Crystallogr., 1983, A39, 876.
13. 4) we could not investigate this point further by IR spectroscopy.
14. Malinovskii, S. T., Simonov, Yu. A., Kudrya, T. N., Chaikovskaya, A. A. and Malinovskii, T. I., Zh. Strukt. Khim., 1984, 25, 130; a phosphorus macrocycle with an intramolecular PS· · ·H - C interaction has been reported in this paper.