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Volumn 120, Issue 12, 1998, Pages 2919-2924

α-stabilization by silyl and phosphino substitution

Author keywords

[No Author keywords available]

Indexed keywords

ARTICLE; BINDING AFFINITY; CHEMICAL BINDING; ELECTRON TRANSPORT; MOLECULAR INTERACTION; SPECTROMETRY;

EID: 0039967294     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja970279s     Document Type: Article
Times cited : (49)

References (54)
  • 1
    • 0000672215 scopus 로고
    • Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Elsevier Science Ltd.; Oxford
    • Colvin, E. W. In Comprehensive Organometallic Chemistry; Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Elsevier Science Ltd.; Oxford, 1995; Vol. 11, pp 131-354.
    • (1995) Comprehensive Organometallic Chemistry , vol.11 , pp. 131-354
    • Colvin, E.W.1
  • 2
    • 0001172865 scopus 로고
    • Trost, B. M., Fleming, I., Eds.; Pergamon: New York
    • Panek, J. S. In Comprehensive Organic Synthesis; Trost, B. M., Fleming, I., Eds.; Pergamon: New York, 1991; Vol 1, pp 579-627.
    • (1991) Comprehensive Organic Synthesis , vol.1 , pp. 579-627
    • Panek, J.S.1
  • 29
    • 2642711816 scopus 로고
    • Ph.D. Thesis, Stanford University
    • Zimmerman, A. H. Ph.D. Thesis, Stanford University, 1977.
    • (1977)
    • Zimmerman, A.H.1
  • 36
    • 0002302717 scopus 로고
    • Bowers, M. T., Ed.; Academic Press: New York
    • Bartmess, J. E.; McIver, R. T., Jr. In Gas-Phase Ion Chemistry; Bowers, M. T., Ed.; Academic Press: New York, 1979; Vol. 2, pp 87-121.
    • (1979) Gas-Phase Ion Chemistry , vol.2 , pp. 87-121
    • Bartmess, J.E.1    McIver Jr., R.T.2
  • 37
    • 2642644685 scopus 로고    scopus 로고
    • note
    • 5
  • 40
    • 2642638884 scopus 로고    scopus 로고
    • note
    • 6 have reported a proton affinity for the trimethylsilylmethyl anion of 387.3 kcal/mol based on bracketing reactions. The standards used in that work were not known to high accuracy, however, so we have chosen to use the value from the thermochemical cycle.
  • 42
    • 2642647960 scopus 로고    scopus 로고
    • note
    • If the stabilities of the neutrals can be accounted for by using simple additivity relationships (such as Benson additivities), then we can attribute the substituent effect on acidity to changes in anion stabilization.
  • 47
    • 2642707648 scopus 로고    scopus 로고
    • note
    • 16-19


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.