Giant ring-shaped building blocks linked to form a layered cluster network with nanosized channels: [MoVI124MoV28O 429(μ3-O)28H14(H 2O)66.5]16-

Chemistry - A European Journal

Volumn 5, Issue 5, 1999, Pages 1496-1502

  Müller, Achim ^a   Krickemeyer, Erich ^a   Bögge, Hartmut ^a   Schmidtmann, Marc ^a   Beugholt, Christian ^a   Das, Samar K ^a   Peters, Frank ^a  

^a BIELEFELD UNIVERSITY   (Germany)

Author keywords

Inorganic rings; Layered compounds; Mixed yalent compounds; Molybdenum blue; Supramolecular chemistry

Indexed keywords

HYDROGEN; METAL OXIDE; MOLYBDENUM; WATER;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL STRUCTURE; CRYSTAL STRUCTURE; CRYSTALLOGRAPHY; ELECTRON TRANSPORT; HYDROPHILICITY; MOLECULAR INTERACTION; NANOPARTICLE; REACTION ANALYSIS; REDUCTION; STRUCTURE ANALYSIS; SYNTHESIS;

EID: 0039243716     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3765(19990503)5:5<1496::AID-CHEM1496>3.0.CO;2-D     Document Type: Article

References (36)

1. For some related aspects see Mixed-Valence Compounds: Theory and Applications in Chemistry, Physics, Geology, and Biology (Ed.: D. B. Brown), Reidel, Dordrecht, 1980; H. H. Kung, Transition Metal Oxides: Surface Chemistry and Catalysis, Elsevier, Amsterdam, 1989; V. E. Henrich, P. A. Cox, The Surface Science of Metal Oxides, Cambridge University Press, Cambridge, 1994.
2. For some related aspects see Mixed-Valence Compounds: Theory and Applications in Chemistry, Physics, Geology, and Biology (Ed.: D. B. Brown), Reidel, Dordrecht, 1980; H. H. Kung, Transition Metal Oxides: Surface Chemistry and Catalysis, Elsevier, Amsterdam, 1989; V. E. Henrich, P. A. Cox, The Surface Science of Metal Oxides, Cambridge University Press, Cambridge, 1994.
3. For some related aspects see Mixed-Valence Compounds: Theory and Applications in Chemistry, Physics, Geology, and Biology (Ed.: D. B. Brown), Reidel, Dordrecht, 1980; H. H. Kung, Transition Metal Oxides: Surface Chemistry and Catalysis, Elsevier, Amsterdam, 1989; V. E. Henrich, P. A. Cox, The Surface Science of Metal Oxides, Cambridge University Press, Cambridge, 1994.
4. A. F. Wells, Structural Inorganic Chemistry, Oxford University Press/Clarendon, Oxford, 1984, pp. 612-619; Low-Dimensional Electronic Properties of Molybdenum Bronzes and Oxides (Ed.: C. Schlenker), Kluwer, Dordrecht, 1989; G. Schwitzgebel, St. Adams, Ber. Bunsenges. Phys. Chem. 1988, 92, 1426-1430; Cl. Ritter, W. Müller-Warmuth, R. Schöllhorn, J. Chem. Phys. 1985, 83, 6130-6138, and references cited therein.
5. A. F. Wells, Structural Inorganic Chemistry, Oxford University Press/Clarendon, Oxford, 1984, pp. 612-619; Low-Dimensional Electronic Properties of Molybdenum Bronzes and Oxides (Ed.: C. Schlenker), Kluwer, Dordrecht, 1989; G. Schwitzgebel, St. Adams, Ber. Bunsenges. Phys. Chem. 1988, 92, 1426-1430; Cl. Ritter, W. Müller-Warmuth, R. Schöllhorn, J. Chem. Phys. 1985, 83, 6130-6138, and references cited therein.
6. A. F. Wells, Structural Inorganic Chemistry, Oxford University Press/Clarendon, Oxford, 1984, pp. 612-619; Low-Dimensional Electronic Properties of Molybdenum Bronzes and Oxides (Ed.: C. Schlenker), Kluwer, Dordrecht, 1989; G. Schwitzgebel, St. Adams, Ber. Bunsenges. Phys. Chem. 1988, 92, 1426-1430; Cl. Ritter, W. Müller-Warmuth, R. Schöllhorn, J. Chem. Phys. 1985, 83, 6130-6138, and references cited therein.
7. A. F. Wells, Structural Inorganic Chemistry, Oxford University Press/Clarendon, Oxford, 1984, pp. 612-619; Low-Dimensional Electronic Properties of Molybdenum Bronzes and Oxides (Ed.: C. Schlenker), Kluwer, Dordrecht, 1989; G. Schwitzgebel, St. Adams, Ber. Bunsenges. Phys. Chem. 1988, 92, 1426-1430; Cl. Ritter, W. Müller-Warmuth, R. Schöllhorn, J. Chem. Phys. 1985, 83, 6130-6138, and references cited therein.
8. Comprehensive Supramolecular Chemistry, Vol. 6, Solid-State Supramolecular Chemistry: Crystal Engineering and Vol. 7, Solid-State Supramolecular Chemistry: Two- and Three-Dimensional Inorganic Networks (Eds.: J. L. Atwood, J. E. D. Davies, D.D. MacNicol, F. Vögtle, J.-M. Lehn), Pergamon/Elsevier, Oxford, 1996; Multifunctional Mesoporous Inorganic Solids (Eds.: C. A. C. Sequeira, M. J. Hudson), Kluwer, Dordrecht, 1993.
9. Comprehensive Supramolecular Chemistry, Vol. 6, Solid-State Supramolecular Chemistry: Crystal Engineering and Vol. 7, Solid-State Supramolecular Chemistry: Two- and Three-Dimensional Inorganic Networks (Eds.: J. L. Atwood, J. E. D. Davies, D.D. MacNicol, F. Vögtle, J.-M. Lehn), Pergamon/Elsevier, Oxford, 1996; Multifunctional Mesoporous Inorganic Solids (Eds.: C. A. C. Sequeira, M. J. Hudson), Kluwer, Dordrecht, 1993.
10. a) A. Müller, E. Krickemeyer, J. Meyer, H. Bögge, F. Peters, W. Plass, E. Diemann, S. Dillinger, F. Nonnenbruch, M. Randerath, C. Menke, Angew. Chem. 1995, 107, 2293-2295; Angew. Chem. Int. Ed. Engl. 1995, 34, 2122-2124;
11. a) A. Müller, E. Krickemeyer, J. Meyer, H. Bögge, F. Peters, W. Plass, E. Diemann, S. Dillinger, F. Nonnenbruch, M. Randerath, C. Menke, Angew. Chem. 1995, 107, 2293-2295; Angew. Chem. Int. Ed. Engl. 1995, 34, 2122-2124;
12. b) A. Müller, F. Peters, M. T. Pope, D. Gatteschi, Chem. Rev. 1998, 98, 239-271; see also compounds listed in Table 1 with corresponding references.
13. In addition to the crystals, amorphous material with identical spectroscopic properties was obtained; however, it cannot be clearly identified. In this context, it should be mentioned that generations of chemists have tried to isolate, without success, pure compounds from reduced molybdate solutions in order to grow crystals and to understand the unusual properties of the related molybdenum-blue species: Gmelins Handbuch der Anorganischen Chemie, Molybdän, VCH, Berlin, 1935, pp. 134-147; Gmelin Handbook of Inorganic Chemistry, Molybdenum Suppl., Vol. B3a, Springer, Berlin, 1987, pp. 61-68. Our earlier conclusion (A. Müller, J. Meyer, E. Krickemeyer, E. Diemann, Angew. Chem. 1996, 108, 1296-1299; Angew. Chem. Int. Ed. Engl. 1996, 35, 1206-1208) that soluble molybdenum blue consists of the linked or nonlinked ring-type species has now been confirmed. [18]
14. In addition to the crystals, amorphous material with identical spectroscopic properties was obtained; however, it cannot be clearly identified. In this context, it should be mentioned that generations of chemists have tried to isolate, without success, pure compounds from reduced molybdate solutions in order to grow crystals and to understand the unusual properties of the related molybdenum-blue species: Gmelins Handbuch der Anorganischen Chemie, Molybdän, VCH, Berlin, 1935, pp. 134-147; Gmelin Handbook of Inorganic Chemistry, Molybdenum Suppl., Vol. B3a, Springer, Berlin, 1987, pp. 61-68. Our earlier conclusion (A. Müller, J. Meyer, E. Krickemeyer, E. Diemann, Angew. Chem. 1996, 108, 1296-1299; Angew. Chem. Int. Ed. Engl. 1996, 35, 1206-1208) that soluble molybdenum blue consists of the linked or nonlinked ring-type species has now been confirmed. [18]
15. In addition to the crystals, amorphous material with identical spectroscopic properties was obtained; however, it cannot be clearly identified. In this context, it should be mentioned that generations of chemists have tried to isolate, without success, pure compounds from reduced molybdate solutions in order to grow crystals and to understand the unusual properties of the related molybdenum-blue species: Gmelins Handbuch der Anorganischen Chemie, Molybdän, VCH, Berlin, 1935, pp. 134-147; Gmelin Handbook of Inorganic Chemistry, Molybdenum Suppl., Vol. B3a, Springer, Berlin, 1987, pp. 61-68. Our earlier conclusion (A. Müller, J. Meyer, E. Krickemeyer, E. Diemann, Angew. Chem. 1996, 108, 1296-1299; Angew. Chem. Int. Ed. Engl. 1996, 35, 1206-1208) that soluble molybdenum blue consists of the linked or nonlinked ring-type species has now been confirmed. [18]
16. In addition to the crystals, amorphous material with identical spectroscopic properties was obtained; however, it cannot be clearly identified. In this context, it should be mentioned that generations of chemists have tried to isolate, without success, pure compounds from reduced molybdate solutions in order to grow crystals and to understand the unusual properties of the related molybdenum-blue species: Gmelins Handbuch der Anorganischen Chemie, Molybdän, VCH, Berlin, 1935, pp. 134-147; Gmelin Handbook of Inorganic Chemistry, Molybdenum Suppl., Vol. B3a, Springer, Berlin, 1987, pp. 61-68. Our earlier conclusion (A. Müller, J. Meyer, E. Krickemeyer, E. Diemann, Angew. Chem. 1996, 108, 1296-1299; Angew. Chem. Int. Ed. Engl. 1996, 35, 1206-1208) that soluble molybdenum blue consists of the linked or nonlinked ring-type species has now been confirmed. [18]
17. B. K. Vainshtein, Fundamentals of Crystals: Symmetry, and Methods of Structural Crystallography, Springer, Berlin, 1994.
18. A. Müller, S. K. Das, V. P. Fedin, E. Krickemeyer, C. Beugholt, H. Bögge, M. Schmidtmann, B. Hauptfleisch, Z. Anorg. Allg. Chem. 1999, 625, in press.
19. A. Müller, M. Koop, H. Bögge, M. Schmidtmann, C. Beugholt, Chem. Commun. 1998, 1501-1502.
20. A. Müller, E. Krickemeyer, S. Q. N. Shah, M. J. Koop, H. Bögge, M. Schmidtmann, Inorg. Chem., in press.
21. A. Müller, E. Krickemeyer, H. Bögge, M. Schmidtmann, F. Peters, C. Menke, J. Meyer, Angew. Chem. 1997, 109, 500-502; Angew. Chem. Int. Ed. Engl. 1997, 36, 484-486.
22. A. Müller, E. Krickemeyer, H. Bögge, M. Schmidtmann, F. Peters, C. Menke, J. Meyer, Angew. Chem. 1997, 109, 500-502; Angew. Chem. Int. Ed. Engl. 1997, 36, 484-486.
23. A. Müller, E. Krickemeyer, H. Bögge, M. Schmidtmann, C. Beugholt, P. Kögerler, C. Lu, Angew. Chem. 1998, 110, 1278-1281; Angew. Chem. Int. Ed. 1998, 57, 1220-1223.
24. A. Müller, E. Krickemeyer, H. Bögge, M. Schmidtmann, C. Beugholt, P. Kögerler, C. Lu, Angew. Chem. 1998, 110, 1278-1281; Angew. Chem. Int. Ed. 1998, 57, 1220-1223.
25. a) A. Müller, C. Beugholt, Nature 1996, 383, 296-297;
26. b) A. Müller, H. Reuter, S. Dillinger, Angew. Chem. 1995, 107, 2505-2539; Angew. Chem. Int. Ed. Engl. 1995, 34, 2328-2361;
27. b) A. Müller, H. Reuter, S. Dillinger, Angew. Chem. 1995, 107, 2505-2539; Angew. Chem. Int. Ed. Engl. 1995, 34, 2328-2361;
28. c) A. Müller, S. Q. N. Shah, H. Bögge, M. Schmidtmann, Nature 1999, 397, 48-50.
29. W. H. Baur, Acta Crystallogr. Sect. B 1992, 48, 745-746.
30. I. D. Brown, in Structure and Bonding in Crystals Vol. II (Eds.: M. O'Keeffe, A. Navrotsky), Academic Press, New York, 1981, pp. 1-30.
31. R. I. Buckley, R. J. H. Clark, Coord. Chem. Rev. 1985, 65, 167-218.
32. Polyoxometalates: From Platonic Solids to Anti-Retroviral Activity (Eds.: M. T. Pope, A. Müller), Kluwer, Dordrecht, 1994; M. T. Pope, A. Müller, Angew. Chem. 1991, 103, 56-70; Angew. Chem. Int. Ed. Engl. 1991, 30, 34-48.
33. Polyoxometalates: From Platonic Solids to Anti-Retroviral Activity (Eds.: M. T. Pope, A. Müller), Kluwer, Dordrecht, 1994; M. T. Pope, A. Müller, Angew. Chem. 1991, 103, 56-70; Angew. Chem. Int. Ed. Engl. 1991, 30, 34-48.
34. Polyoxometalates: From Platonic Solids to Anti-Retroviral Activity (Eds.: M. T. Pope, A. Müller), Kluwer, Dordrecht, 1994; M. T. Pope, A. Müller, Angew. Chem. 1991, 103, 56-70; Angew. Chem. Int. Ed. Engl. 1991, 30, 34-48.
35. M. B. Robin, P. Day, Adv. Inorg. Chem. Radiochem. 1967, 10, 247-422.
36. Note added in proof: In the meantime we were able to obtain the layer-type compound in a facile synthesis in high yield and in pure and crystalline form in the presence of an electron-donating ligand; this changes the property of the cluster surface: A. Müller, S. K. Das, H. Bögge, C. Beugholt, M. Schmidtmann, Chem. Commun., in press.