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v reagents in organic synthesis, see a) T. Arnauld, D. H. R. Barton, J.-F. Normant, E. Doris, J. Org. Chem. 1999, 64, 6915-6917; b) J.-P. Finet, Chem. Rev. 1989, 89, 1487-1501.
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note
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b) Cambridge Structural Database codes a) NAXVUD; b) NAX-WEO, NAXVOX.
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15
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0038230633
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note
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3]2. Here, X-ray crystallography confirms the presence of a homochiral diastereoisomer. Detailed studies of similar β-stereogenic carboxy-esters are underway.
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Sb: FACFSB
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For example, see D. P. Bullivant, M. F. A. Dove, M. J. Haley, J. Chem. Soc. Dalton Trans. 1980, 109-114 (Sb: FACFSB); E. Papavinasam, S. Natarjan, Z. Kristallogr. 1985, 172, 251-256 (Cu: FOVMOS); P. J. Bonitatebus Jr., W. H. Armstrong, Chem. Commun. 1999, 55-56 (V: HOQCEV); A. Escuer, E. Penalba, R. Vicente, X, Solans, M. Font-Bardia, J. Chem. Soc. Dalton Trans. 1997, 2315-2319 (Cu: NAVHAT. NAVHEX); C. He, S. J. Lippard, J Am. Chem. Soc. 1998, 120, 105-113 (Co: NEWTUE).
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0037555205
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Cu: FOVMOS
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For example, see D. P. Bullivant, M. F. A. Dove, M. J. Haley, J. Chem. Soc. Dalton Trans. 1980, 109-114 (Sb: FACFSB); E. Papavinasam, S. Natarjan, Z. Kristallogr. 1985, 172, 251-256 (Cu: FOVMOS); P. J. Bonitatebus Jr., W. H. Armstrong, Chem. Commun. 1999, 55-56 (V: HOQCEV); A. Escuer, E. Penalba, R. Vicente, X, Solans, M. Font-Bardia, J. Chem. Soc. Dalton Trans. 1997, 2315-2319 (Cu: NAVHAT. NAVHEX); C. He, S. J. Lippard, J Am. Chem. Soc. 1998, 120, 105-113 (Co: NEWTUE).
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0345472102
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V: HOQCEV
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For example, see D. P. Bullivant, M. F. A. Dove, M. J. Haley, J. Chem. Soc. Dalton Trans. 1980, 109-114 (Sb: FACFSB); E. Papavinasam, S. Natarjan, Z. Kristallogr. 1985, 172, 251-256 (Cu: FOVMOS); P. J. Bonitatebus Jr., W. H. Armstrong, Chem. Commun. 1999, 55-56 (V: HOQCEV); A. Escuer, E. Penalba, R. Vicente, X, Solans, M. Font-Bardia, J. Chem. Soc. Dalton Trans. 1997, 2315-2319 (Cu: NAVHAT. NAVHEX); C. He, S. J. Lippard, J Am. Chem. Soc. 1998, 120, 105-113 (Co: NEWTUE).
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0032515411
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Cu: NAVHAT, NAVHEX
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For example, see D. P. Bullivant, M. F. A. Dove, M. J. Haley, J. Chem. Soc. Dalton Trans. 1980, 109-114 (Sb: FACFSB); E. Papavinasam, S. Natarjan, Z. Kristallogr. 1985, 172, 251-256 (Cu: FOVMOS); P. J. Bonitatebus Jr., W. H. Armstrong, Chem. Commun. 1999, 55-56 (V: HOQCEV); A. Escuer, E. Penalba, R. Vicente, X, Solans, M. Font-Bardia, J. Chem. Soc. Dalton Trans. 1997, 2315-2319 (Cu: NAVHAT. NAVHEX); C. He, S. J. Lippard, J Am. Chem. Soc. 1998, 120, 105-113 (Co: NEWTUE).
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0032515411
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Co: NEWTUE
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For example, see D. P. Bullivant, M. F. A. Dove, M. J. Haley, J. Chem. Soc. Dalton Trans. 1980, 109-114 (Sb: FACFSB); E. Papavinasam, S. Natarjan, Z. Kristallogr. 1985, 172, 251-256 (Cu: FOVMOS); P. J. Bonitatebus Jr., W. H. Armstrong, Chem. Commun. 1999, 55-56 (V: HOQCEV); A. Escuer, E. Penalba, R. Vicente, X, Solans, M. Font-Bardia, J. Chem. Soc. Dalton Trans. 1997, 2315-2319 (Cu: NAVHAT. NAVHEX); C. He, S. J. Lippard, J Am. Chem. Soc. 1998, 120, 105-113 (Co: NEWTUE).
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0037893176
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note
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2, M = Sb, Bi] were derived using the standard B3LYP form of DFT, with the 6-31G* basis set on all atoms except Sb and Bi, where a triple-zeta form of the LanL2DZ core potential and associated basis were used. These calculations were carried out using the Jaguar program (v4.2), and the structures used were optimized at the same level of theory.
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IUPAC, Chemical data series no. 23, Pergamon, Oxford
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