Calcium-catalyzed selective and quantitative transformation of CH4 and CO into acetic acid

Angewandte Chemie - International Edition

Volumn 39, Issue 14, 2000, Pages 2475-2478

  Asadullah, Mohammad ^a   Kitamura, Tsugio ^a   Fujiwara, Yuzo ^a  

^a KYUSHU UNIVERSITY   (Japan)

Author keywords

C H activation; Calcium; Carboxylation; Carboxylic acids; Homogeneous catalysis; Methane

Indexed keywords

ACETIC ACID; CALCIUM; CARBON MONOXIDE; METHANE;

ARTICLE; BIOTRANSFORMATION; CARBOXYLATION; CATALYSIS; CATALYST; CHEMICAL BINDING; CHEMICAL REACTION KINETICS; REACTION ANALYSIS; STEREOCHEMISTRY;

EID: 0034679514     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/1521-3773(20000717)39:14<2475::AID-ANIE2475>3.0.CO;2-Y     Document Type: Article

References (28)

1. a) M. G. Axelrod, A. M. Gaffney, R. Pitchai, J. A. Sofranko, Natural Gas Conversion II (Eds.: H. E. Cury-Hyde, R. F. Howe), Elsevier, Amsterdam, 1994, p. 93;
2. b) C. Starr, M. F. Searl, S. Alpert, Science 1992, 256, 981.
3. a) Activation and Functionalization of Alkanes (Ed.: C. L. Hill), Wiley, New York, 1989;
4. b) A. E. Shilov, Activation of Saturated Hydrocarbons by Transition Metal Complexes, D. Reidel, Dordrecht, 1984;
5. c) G. A. Olah, A. Molnár, Hydrocarbon Chemistry, Wiley, New York, 1995;
6. d) Natural Gas Conversion V (Eds.: A. Parmaliana, D. Sanfilippo, F. Frusteri, A. Vaccari, F. Arena), Elsevier, Amsterdam, 1998.
7. a) R. G. Bergman, Science 1984, 223, 902;
8. b) K. Tomishige, Y. Himeno, O. Yamazaki, Y. Chen, T. Wakatsuki, K. Fujimoto, Kinet. Catal. 1999, 40, 388;
9. c) K. Tomishige, Y. Chen, K. Fujimoto, J. Catal. 1999, 181, 91;
10. d) A. Bagno, J. Bukala, G. A. Olah, J. Org. Chem. 1990, 55, 4284;
11. e) R. H. Crabtree, Chem. Rev. 1995, 95, 987;
12. f) G. V. Nizova, G. Süss-Fink, G. B. Shul'pin, Tetrahedron 1997, 53, 3603.
13. T. Nishiguchi, K. Nakata, K. Takaki, Y. Fujiwara, Chem. Lett. 1992, 1141.
14. M. Asadullah, Y. Taniguchi, T. Kitamura, Y. Fujiwara, Appl. Organomet. Chem. 1998, 12, 277.
15. a) M. Asadullah, T. Kitamura, Y. Fujiwara, Appl. Organomet. Chem. 1999, 13, 539;
16. b) M. Asadullah, T. Kitamura, Y. Fujiwara, Chem. Lett. 1999, 449.
17. a) A. Bagno, J. Bukala, G. A. Olah, J. Org. Chem. 1990, 55, 4284;
18. b) H. Hogeveen, J. Lukas, C. F. Roobeek, J. Chem. Soc. Chem. Commun. 1969, 920.
19. M. Lin, A. Sen, Nature 1994, 368, 613.
20. 1 is lower than that required for a practical process. Attempts to increase the volumetric productivity by optimizing the reaction conditions and the apparatus are underway.
21. M. Lin, T. Hogan, A. Sen, J. Am. Chem. Soc. 1997, 119, 6048.
22. a) G. V. Nizova, G. Süss-Fink, S. Stanislas, G. B. Shul'pin, Chem. Commun. 1998, 1885;
23. b) K. Nagahara, I. Ryu, N. Kambe, M. Komatsu, N. Sonoda, J. Org. Chem. 1995, 60, 7384;
24. c) A. P. E. York, J. B. Claridge, A. J. Brungs, S. C. Tsang, M. L. H. Green, Chem. Commun. 1997, 39;
25. d) J. H. Bitter, K. Seshan, J. A. Lercher, J. Catal. 1997, 171, 279;
26. e) Y. Lu, J. Xue, Y. Liu, S. Shen, Chem. Lett. 1997, 515;
27. f) U. Olsbye, T. Wurzel, L. Mleczko, Ind. Eng. Chem. Res. 1997, 36, 5180;
28. g) M. C. J. Bradford, M. A. Vannice, J. Catal. 1998, 173, 157.