Intramolecular hydrogen bonding in transition metal clusters: NMR evidence for an Os-H⋯H-S interaction in H(μ-H)Os3(CO)10(HSR) (R = ethyl, cyclopentyl)

Inorganica Chimica Acta

Volumn 351, Issue 1, 2003, Pages 251-255

  Aime, Silvio ^a   Chierotti, Michele R ^a   Gobetto, Roberto ^a   Russo, Andrea ^a   Stchedroff, Marc J ^a  

^a UNIVERSITY OF TURIN   (Italy)

Author keywords

Cluster; NMR; Osmium; T1; Thiol; Unconventional hydrogen bond

Indexed keywords

HYDRIDES; LIGANDS; NUCLEAR MAGNETIC RESONANCE; OSMIUM; TRANSITION METALS;

CLUSTER; DIPOLAR CONTRIBUTION; HYDROGEN-HYDROGEN INTERACTION; INTRAMOLECULAR HYDROGEN BONDING; INTRAMOLECULAR PROTON TRANSFER; LONGITUDINAL RELAXATION TIME; THIOL; TRANSITION-METAL CLUSTERS;

HYDROGEN BONDS;

CARBONYL DERIVATIVE; HYDROGEN; LIGAND; THIOL; THIOL DERIVATIVE; TRANSITION ELEMENT;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CHEMICAL REACTION; HYDROGEN BOND; ISOLATION PROCEDURE; ISOMER; LOW TEMPERATURE; MOLECULAR INTERACTION; POLARIZATION; PROTON TRANSPORT;

EID: 0038785629     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0020-1693(03)00120-8     Document Type: Article

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