Role of Os-H⋯H-N interactions in directing the stereochemistry of carbonyl cluster hydride derivatives

Organometallics

Volumn 16, Issue 24, 1997, Pages 5140-5141

  Aime, Silvio ^a   Gobetto, Roberte ^a   Valls, Esteve ^a  

^a UNIVERSITY OF TURIN   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000688139     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om9706370     Document Type: Article

References (9)

1. Richardson, T. B.; DeGala, S.; Crabtree, R. H.; Siegbahn, P. E. M. J. Am. Chem. Soc. 1995, 117, 12875.
2. Crabtree, R. H.; Siegbahn, P. E. M.; Eisenstein, O.; Rheingold, A. L.; Koetzle, T. F. Ace. Chem. Res. 1996, 29, 348.
3. Adams, R. D.; Golembeski, N. M. Inorg. Chem. 1979, 18, 1909.
4. Anslyn, E. V.; Green, M.; Nicola, G.; Rosenberg, E. Organometallics 1991, 10, 2600.
5. Keister, J. B.; Shapley, J. R. Inorg. Chem. 1982, 21, 3304.
6. Desrosiers, P. J.; Cai, L.; Lin, Z.; Richards, R.; Halpern, J. J. Am. Chem. Soc. 1991, 113, 4173.
7. Abragam, A. The Principles of Nuclear Magnetism; Oxford University Press: Oxford, U.K., 1973; Chapter 8.
8. The factor 1.0625 accounts for the residual dipolar contribution arising from the interaction with the deuterium magnetic momentum.
9. Although this product can be isolated upon slow evaporation of the solvent and the excess amine, we have been unable to obtain until now suitable crystals for an X-ray diffraction study.