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Volumn 107, Issue 25, 2003, Pages 5042-5048

Mechanism of pyrrolyl oxidation in star-shaped compounds

Author keywords

[No Author keywords available]

Indexed keywords

BENZENE; ELECTROCHEMISTRY; ORGANIC CONDUCTORS; OXIDATION; PHOTOLYSIS; POLYMERIZATION; POSITIVE IONS;

EID: 0038756400     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp034417d     Document Type: Article
Times cited : (33)

References (55)
  • 35
    • 0030172783 scopus 로고    scopus 로고
    • The enhancement of solubility is well illustrated with hexakis(4-octylphenyl)benzene (alkylated hexabenzocoronene), which is more soluble than hexabenzocoronene. See Herwig, P.; Kayser, C. W.; Mullen, C.; Spiess, H. W. Adv. Mater. 1996, 8, 510.
    • (1996) Adv. Mater. , vol.8 , pp. 510
    • Herwig, P.1    Kayser, C.W.2    Mullen, C.3    Spiess, H.W.4
  • 36
    • 0038192982 scopus 로고    scopus 로고
    • note
    • -1 22b,c
  • 39
    • 0037855232 scopus 로고    scopus 로고
    • note
    • For aromatic compounds such as pyrrole derivatives, the decay constant increases when the pH is increased, indicating rapid deprotonation of the product obtained from the condensation of the two radical cations when second-order coupling reactions occur. (See ref 24.)
  • 49
    • 0038192983 scopus 로고    scopus 로고
    • note
    • The oxidation of HPyB to HpyB6σ requires the exchange of 12 electrons and the loss of 12 protons per molecule. The total expected charge should be slightly higher because HPyB6σ should finally be in the oxidized form at the oxidation potential of HPyB.
  • 51
    • 0037855233 scopus 로고    scopus 로고
    • note
    • See, for example, the voltammograms in ref 6g.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.