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0347962169
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note
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a values of β-protonated pyrrole (-5.9) and acetonitrile (-4.2, listed in Table 1) are not convincing. It is, however, well-known that the oligomer, polymer, and salts of pyrrole dimer are readily formed in dilute aqueous acid, whereas nitriles can be only protonated by sufficiently strong acids under anhydrous conditions in aprotic media and do not form salts with mineral acids in aqueous media. These facts substantiate the view that pyrrole is a relatively stronger base than acetonitrile.
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28
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0346070747
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note
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"Pyridin" here means both substituted and unsubstituted species.
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40
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0344286342
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85087251696
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