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Volumn 103, Issue 40, 1999, Pages 8451-8457

Electropolymerization of Pyrrole and Electrochemical Study of Polypyrrole. 3. Nature of "Water Effect" in Acetonitrile

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Indexed keywords


EID: 0000478627     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp990162l     Document Type: Article
Times cited : (96)

References (43)
  • 26
    • 0347962169 scopus 로고    scopus 로고
    • note
    • a values of β-protonated pyrrole (-5.9) and acetonitrile (-4.2, listed in Table 1) are not convincing. It is, however, well-known that the oligomer, polymer, and salts of pyrrole dimer are readily formed in dilute aqueous acid, whereas nitriles can be only protonated by sufficiently strong acids under anhydrous conditions in aprotic media and do not form salts with mineral acids in aqueous media. These facts substantiate the view that pyrrole is a relatively stronger base than acetonitrile.
  • 38
    • 0346070747 scopus 로고    scopus 로고
    • note
    • "Pyridin" here means both substituted and unsubstituted species.
  • 42
    • 85087251696 scopus 로고    scopus 로고
    • note
    • 40b


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.