Synthesis and characterization of sterically hindered arylsilanes containing the 2,4,6-trimethoxyphenyl ligand (TMP): X-ray structures of (TMP)SiH3, (TMP)2SiH2, and (TMP)3SiH

Journal of Organometallic Chemistry

Volumn 588, Issue 1, 1999, Pages 51-59

  Braddock Wilking, Janet ^a   Levchinsky, Yanina ^a   Rath, Nigam P ^a  

^a UNIVERSITY OF MISSOURI ST LOUIS   (United States)

Author keywords

Arylsilane; Silicon; Solid state structure; Steric hindrance

Indexed keywords

EID: 0038624572     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-328X(99)00345-9     Document Type: Article

References (37)

1. 2 (Mes=2,4,6-trimethylphenyl); R. West, M.J. Fink, J. Michl, Science 214 (1981) 1343.
2. J. Braddock-Wilking, M. Schiesher, L. Brammer, J. Huhmann, R. Shaltout, J. Organomet. Chem. 499 (1995) 89.
3. For recent reviews on penta- and hexacoordinated silicon compounds see: (a) C. Chuit, R.J.P. Corriu, C. Reye, J.C. Young, Chem. Rev. 93 (1993) 1371. (b) R.R. Holmes, Chem. Rev. 90 (1990) 17.
4. For recent reviews on penta- and hexacoordinated silicon compounds see: (a) C. Chuit, R.J.P. Corriu, C. Reye, J.C. Young, Chem. Rev. 93 (1993) 1371. (b) R.R. Holmes, Chem. Rev. 90 (1990) 17.
5. (a) J.Y. Corey, C.S. John, M.C. Ohmsted, L.S. Chang, J. Organomet. Chem. 394 (1986) 93.
6. (b) A. Benouargha, D. Boulahia, B. Boutevin, G. Caporiccio, F. Guida-Pietrasanta, A. Ratsimihety, Phosphorus Sulfur Silicon 113 (1996) 79.
7. Corey J.Y., Braddock-Wilking J. Chem. Rev. 99:1999;175.
8. (a) T.D. Tilley, Comments Inorg. Chem. 10 (1990) 49.
9. (b) J.Y. Corey, in: G. Larson (Ed.), Advances in Silicon Chemistry, vol. 1, JAI Press, Greenwich, CT, 1991, pp. 327.
10. See for example: (a) F.T. Edelmann, Main Group Met. Chem. 17 (1994) 67. (b) F.T. Edelmann, Comments Inorg. Chem. 12 (1992) 259.
11. See for example: (a) F.T. Edelmann, Main Group Met. Chem. 17 (1994) 67. (b) F.T. Edelmann, Comments Inorg. Chem. 12 (1992) 259.
12. (a) M. Wada, S. Higashizaki, A. Tsuboi, J. Chem. Res. (S) (1985) 38.
13. (b) M. Wada, S. Higashizaki, J. Chem. Soc. Chem. Commun. (1984) 482.
14. (a) G. Van Koten, A.J. Leusink, J.G. Noltes, J. Organomet. Chem. 85 (1975) 105.
15. (b) A.J. Leusink, G. Van Koten, J.G. Noltes, J. Organomet. Chem. 56 (1973) 379.
16. (c) F.A. Cotton, A.A. Koc, M. Millar, M. Inorg. Chem. 17 (1978) 2087.
17. For a related example, see: H. Oehme, H. Weiss, J. Organomet. Chem. 319 (1987) C16.
18. E.A. Williams, in: S. Patai, Z. Rappoport (Eds.), The Chemistry of Organic Silicon Compounds, vol. 8, Wiley, New York, 1989, pp. 511.
19. H with the subscripts referring to the deuterated (D) or protonated (H) species. The (P-1) term refers to the (parent ion-1) peak in the mass spectrum.
20. Brelier C., Carre F., Corriu R.J.P., Poirier M., Royo G., Zwecker J. Organometallics. 8:1989;1831.
21. Brelier C., Carre F., Corriu R.J.P., Royo G., Wong chi Man M. Organometallics. 13:1994;307.
22. Kawachi A., Tanaka Y., Tamao K. Organometallics. 16:1997;5102.
23. Allemand J., Gerdil R. Cryst. Struct. Commun. 8:1979;927.
24. Bondi A. J. Phys. Chem. 68:1964;441.
25. Klebe G. J. Organomet. Chem. 293:1985;147.
26. Buijink J.-K., Noltemeyer M., Edelmann F.T. J. Fluor. Chem. 61:1993;51.
27. Carré F., Chuit C., Corriu R.J.P., Mehdi A., Reyé C. Angew. Chem. Int. Ed. Engl. 33:1994;1097.
28. 2 compound was recently reported: J.E. Bender IV, M.M. Banaszak Holl, J.W. Kampf, Organometallics 17 (1998) 5166.
29. (b) The corresponding tin and lead derivatives have also been prepared: H. Grützmacher, H. Pritzkow, F.T. Edelmann, Organometallics 10 (1991) 23.
30. (c) S. Broker, J.-K. Buijink, F.T. Edelman, Organometallics 10 (1991) 25.
31. F ligand: K.K. Klinkhammer, T.F. Fässler, H. Grützmacher, Angew. Chem. Int. Ed. Engl. 37 (1998) 124; and the other the 2,4,6-tris(triisopropylphenyl) substituent.
32. (e) M. Stürmann, W. Saak, H. Marsmann, M. Weidenbruch, Angew. Chem. Int. Ed. Engl. 38 (1999) 187.
33. Schluter R.D., Cowley A.H., Atwood D.A., Jones R.A., Bond M.R., Carrano C.J. J. Am. Chem. Soc. 115:1993;2070.
34. Beilstein, fourth ed., 6(8) (1967) 6305.
35. Bruker Analytical X-ray, Madison, WI, 1998.
36. Blessing R.H. Acta Crystallogr. A51:1995;33.
37. G.M. Sheldrick, Bruker Analytical X-ray Division, Madison, WI, 1998.