Medium-sized cyclophanes. Part 62:1 formylation of anti-[n.2]metacyclophanes - Through-space electronic interactions between two benzene rings

Canadian Journal of Chemistry

Volumn 81, Issue 3, 2003, Pages 244-252

  Yamato, Takehiko ^a   Furukawa, Tsuyoshi ^a   Tanaka, Kan ^b   Ishi i, Tsutomu ^c   Tashiro, Masashi ^c  

^a SAGA UNIVERSITY   (Japan)

^b TOHWA UNIVERSITY   (Japan)

^c KYUSHU UNIVERSITY   (Japan)

Author keywords

complex intermediates; Cyclophanes; Electrophilic aromatic substitution; ipso formylation; Strained molecules; Through space electronic interactions

Indexed keywords

BENZENE; ETHERS; REACTION KINETICS;

CYCLOPHANES;

AROMATIC COMPOUNDS;

2,7 BIS TERT BUTYL 10B,10C DIMETHYL 10B,10C DIHYDROPYRENE; 5 TERT BUTYL 13 FORMYL 8,16 DIMETHYL[2.2]METACYCLOPHANE; 5 TERT BUTYL 8,16 DIMETHYL 13 (3 METHYL 1 BUTEN 2 YL)[2.2]METACYCLOPHANE; 5,13 BIS TERT BUTYL 1 HYDROXY 8,16 DIMETHYL[2.2]METACYCLOPHANE; 5,13 BIS TERT BUTYL 8,16 DIMETHYL[2.2]METACYCLOPHANE; 5,13 DIFORMYL 8,16 DIMETHYL[2.2]METACYCLOPHANE; 6,14 BIS TERT BUTYL 7 FORMYL 9,17 DIMETHYL[3.2]METACYCLOPHANE; 6,14 BIS TERT BUTYL 9,17 DIMETHYL[3.2]METACYCLOPHANE; [4.2]METACYCLOPHANE; BENZENE DERIVATIVE; CYCLOPHANE DERIVATIVE; DIMETHYL ETHER; PYRENE DERIVATIVE; TERT BUTYL METHYL ETHER; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL INTERACTION; CHEMICAL REACTION; CHEMICAL STRUCTURE; ELECTRON TRANSPORT; MELTING POINT; QUANTUM YIELD;

EID: 0038613008     PISSN: 00084042     EISSN: None     Source Type: Journal    
DOI: 10.1139/v03-023     Document Type: Article

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