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There are two possible isomers with respect to the orientation of 3,5-di-tert-butyldioxolene ligands of 1, 3, and 5. Complexes depicted in Figure 1 predominantly crystallized under experimental conditions.
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The signal of the DMPO spin adduct increased linearly with an increase in the DMPO concentration.
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2/2-methoxyethanol (10:1 v/v) solution of 5 also showed the EPR signal of Figure 10A at 3.9 K.
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note
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·-] were essentially consistent with those of the values determined from signals around g = 4.
-
-
-
|