Energy conversion from proton gradient to electricity based on characteristic redox behavior of an aqua ruthenium complex with a quinone ligand

Bulletin of the Chemical Society of Japan

Volumn 73, Issue 3, 2000, Pages 607-614

  Tsuge, Kiyoshi ^a   Kurihara, Masato ^a   Tanaka, Koji ^a  

^a INSTITUTE FOR MOLECULAR SCIENCE   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

QUINONE DERIVATIVE; RUTHENIUM;

ABSORPTION SPECTROSCOPY; ARTICLE; CHEMICAL ANALYSIS; CHEMICAL REACTION; COMPLEX FORMATION; ELECTRICITY; ELECTROCHEMISTRY; ENERGY CONVERSION; OXIDATION REDUCTION REACTION; PROTON TRANSPORT; SYNTHESIS;

EID: 0034023812     PISSN: 00092673     EISSN: None     Source Type: Journal    
DOI: 10.1246/bcsj.73.607     Document Type: Article

References (32)

1. A. L. Lehninger, "Principles of Biochemistry," Worth Publishers, New York (1982).
2. H. Noji, R. Yasuda, M. Yoshida, and K. Kinoshita, Jr., Nature, 386, 299 (1997).
3. J. E. Walker, I. M. Fearnley, R. Lutter, R. J. Todd, and M. J. Runswick, Philos. Trans. R. Soc. London, 326, 367 (1990).
4. P. D. Boyer, Biochim. Biophys. Acta, 1140, 215 (1993).
5. P. Mitchell, Science, 206, 1148 (1979).
6. P. Mitchell, Nature, 191, 144 (1961).
7. H. M. Papee, W. J. Canady, and K. J. Laidler, Can. J. Chem., 34, 1677 (1956).
8. H. S. Harned and B. B. Owen, Chem. Rev., 25, 31 (1939).
9. J. Burgess, in "Comprehensive Coordination Chemistry," ed by G. Wilkinson, R. D. Gillard, and J. A. McCleverty, Pergamon, Oxford (1987), Vol. 2, pp. 295-314.
10. C.-M. Che and V. W.-W. Yam, Adv. Inorg. Chem., 39, 233 (1992).
11. E. L. Lebeau, S. A. Adeyemi, and T. J. Meyer, Inorg. Chem., 37, 6476 (1998).
12. A. Dovletoglou, S. A. Adeyemi, and T. J. Meyer, Inorg. Chem., 35, 4120 (1996).
13. M. S. Ram, L. M. Skeens-Jones, C. S. Johnson, X. L. Zhang, C. Stern, D. I. Yoon, D. Selmarten, and J. T. Hupp, J. Am. Chem. Soc., 117, 1411 (1995).
14. E. P. Kelson, L. M. Henling, W. P. Schaefer, J. A. Labinger, and J. E. Bercaw, Inorg. Chem., 32, 2863 (1993).
15. K. Tsuge and K. Tanaka, Chem. Lett., 1998, 1069.
16. M. Kurihara, S. Daniele, K. Tsuge, H. Sugimoto, and K. Tanaka, Bull. Chem. Soc. Jpn., 71, 867 (1998).
17. K. J. Takeuchi, M. S. Thompson, D. W. Pipes, and T. J. Meyer, Inorg. Chem., 23, 1845 (1984).
18. S. Bhattacharya, Polyhedron, 13, 451 (1994).
19. M. Haga, E. S. Dodsworth, and A. B. P. Lever, Inorg. Chem., 25, 447 (1986).
20. + exists simultaneously on the addition of base.
21. II-semiquinone in this hydroxo complex. The intra-molecular electron transfer from electron-rich hydroxo ligand to quinone ligand should cause such modification of oxidation state. The detailed mechanism of intra-molecular electron transfer is now under investigation.
22. 2+ is consumed in a reaction with acetone due to lability of the solvent toward the base.
23. The deprotonation of hydroxo ligand leaves a lone pair on oxo ligands. We supposed the intra-molecular electron transfer from the lone pair of oxo ligand to quinone ligand as in the case on the conversion of aqua ligand to hydroxo ligand.
24. R. A. Binstead, M. E. McGuire, A. Dovletoglou, W. K. Seok, L. E. Roecker, and T. J. Meyer, J. Am. Chem. Soc., 114, 173 (1992).
25. W. K. Seok and T. J. Meyer, J. Am. Chem. Soc., 110, 7358 (1988).
26. L. Roecker and T. J. Meyer, J. Am. Chem. Soc., 109, 746 (1987).
27. J. Gilbert, L. Roecker, and T. J. Meyer, Inorg. Chem., 26, 1126 (1987).
28. M. S. Thompson and T. J. Meyer, J. Am. Chem. Soc., 104, 4106 (1982).
29. J. A. Gilbert, S. W. Gersten, and T. J. Meyer, J. Am. Chem. Soc., 104, 6872 (1982).
30. 2+, the hydroxo compounds were also reactive and the aqua complex formed. In the case of quinone complex the hydroxo complexes are stable judged from Vis-NIR spectra and CVs.
31. Since acetone is not very stable in basic condition, the unstable species derived from acetone is regarded to be oxidized. Oxidation with this complex is now under investigation.
32. 2O, the pH gradient can be catalytically converted into electricity with two hydrogen electrodes.