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0035921540
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This approach was recently taken by Harman: Meiere, S. H.; Brooks, B. C.; Gunoe, T. B.; Carrig, E. H.; Sabat, M.; Harman, \W. \D
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This approach was recently taken by Harman: Meiere, S. H.; Brooks, B. C.; Gunoe, T. B.; Carrig, E. H.; Sabat, M.; Harman, \W. \D Organometallics 2001, 20, 3661.
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15
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0037597809
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note
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3).
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16
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0037597815
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note
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Crystallographic data for 2 (-162 °C): a = 10.6141(4) Å b = 11.1066(4) Å, c = 17.6560(7) Å α = 71.902(1)°, β = 75.498(1)°, γ = 78.701(1)° with Z = 2 in space group P1̄. R(F) = 0.0178 for 9824 reflections with I > 2.33σ(I). Crystallographic data for 6(-158 °C): a =11.2777(3) Å b = 11.5672(3) Å, c = 15.5630(5) Å α = 92.868(1)°C, β = 94.163(1)°, γ = 109.906(1)°, Z = 2 in space group P1̄. R(F) = 0.0153 for 9898 reflections with I > 3σ(I).
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17
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0001666058
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For discussion of related distortions involvng metal hydrides see ref 2b and
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For discussion of related distortions involvng metal hydrides see ref 2b and: (a) Clark, J. R.; Pulvirenti, A. L.; Fanwick, P. E.; Sigalas, M.; Eisenstein, O.; Rothwell, I. P. Inorg. Chem. 1997, 36, 3623.
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0034189897
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For selected reports relevant to intra-and intermolecular C-H activation by Re, Ru, and Os polyhydrides see
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For selected reports relevant to intra-and intermolecular C-H activation by Re, Ru, and Os polyhydrides see: (a) Baudry, D.; Ephritikhine, M.; Felkin, H.; Zakrzewski, J. J. Tetrahedron Lett. 1984, 25, 1283.
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0001463882
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On the formation of Re carbynes from alkynes and Os carbynes from alkenes and alkynes see: (a) Leeaphon, M.; Ondracek, A. L.; Thomas, R. J.; Fanwick, P. E.; Walton, R. A. J. Am. Chem. Soc. 1995, 117, 9715.
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0001759822
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(e) Buil, M. L.; Eisenstein, O.; Esteruelas, M. A.; Garcia-Yebra, C; Gutierrez-Puebla, E.; Olivan, M.; Onate, E.; Ruiz, N.; Tajada, M. A. Organometallics 1999, 18, 4949.
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34
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0038611947
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note
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Only ethylene was detected among trapped volatiles from the thermolysis of 6.
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35
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0001243320
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3 has been reported: (a) Shih, K.-Y.; Tortland, K.; Seidel, S.W.; Schrock, R. R. J. Am. Chem. Soc. 1994, 116, 12103.
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4344714196
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For examples of relative stability of the carbene and hydridocarbyne substructures on Ta and W see: (a) Fellmann, J. D.; Turner, H. W.; Schrock, R. R. J. Am. Chem. Soc. 1980, 102, 6609.
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