1,4-Addition of diethylzinc to cyclohexenone catalyzed by CuOTf-sulfonamide combined system. Evidence supporting a concerted mechanism

Chemistry Letters

Volumn 32, Issue 3, 2003, Pages 224-225

  Nakano, Keiji ^a   Bessho, Yuhki ^a   Kitamura, Masato ^a  

^a NAGOYA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CARBON; CARBON 13; CHEMICAL COMPOUND; COPPER; COPPER ION; CYCLOHEXONE; DIETHYLZINC; ISOTOPE; ORGANOMETALLIC COMPOUND; SULFONAMIDE; UNCLASSIFIED DRUG;

ADDITION REACTION; ARTICLE; CATALYSIS; CHEMICAL ANALYSIS; CHEMICAL PARAMETERS; CHEMICAL PROCEDURES; STOICHIOMETRY;

EID: 0038467615     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.2003.224     Document Type: Article

References (28)

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25. The equilibrium isotope effect is also observable, but the degree of contribution is supposed not to become significant due to little change of the zero-point vibration pattern at C(1) and C(2) at the ground state.
26. The reaction condition is in the range of that described in Ref. 2.
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28. The present result is also consistent with the view of the concerted transfer of Cu atom via 5 followed by low energy reductive elimination of 7. For more information, a detailed analysis of the product at the initial stage is required.