[(μ2-CO)Cp2(OC)2Fe2][Cp(OC) 2Fe]SiH: A SiH-functionalized tris(metallo)silane. Synthesis from [Cp(OC)2Fe]2SiH21

Organometallics

Volumn 21, Issue 14, 2002, Pages 2830-2832

  Malisch, Wolfgang ^a   Vögler, Matthias ^a   Käb, Harald ^a   Wekel, Hans Ulrich ^a  

^a UNIVERSITY OF WÜRZBURG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

METALATION;

HYDROGEN; HYDROGEN BONDS; ISOMERS; MOLECULAR STRUCTURE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PHOTOCHEMICAL REACTIONS; PROTONS; SILANES; SYNTHESIS (CHEMICAL);

ORGANOMETALLICS;

EID: 0038392460     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0201922     Document Type: Article

References (39)

1. 2. In Organosilicon Chemistry IV: From Molecules to Materials; Auner, N., Weis, J., Eds.; Wiley-VCH: Weinheim, Germany, 1999; pp 446-450.
2. (a) Corey, J. Y.; Braddock-Wilking, J. Chem. Rev. 1999, 99, 175-292.
3. (b) Cundy, C. S.; Kingston, B. M.; Lappert, M. F. Adv. Organomet. Chem. 1973, 11, 253-330.
4. (c) Tilley, T. D. In The Chemistry of Organic Silicon Compounds; Patai, S., Rappoport, Z., Eds.; Wiley-Interscience: Chichester, U.K., 1989; Chapter 24.
5. (a) Malisch, W.; Wekel, H.-U.; Grob, I.; Köhler, F. H. Z. Naturforsch. 1982, 37B, 601-609.
6. (b) Schmitzer, S.; Weis, U.; Käb, H.; Buchner, W.; Malisch, W.; Polzer, T.; Posset, U.; Kiefer, W. Inorg. Chem. 1993, 32, 303-309.
7. (c) Malisch, W.; Lankat, R.; Schmitzer, S.; Pikl, R.; Posset, U.; Kiefer, W. Organometallics 1995, 14, 5622-5627.
8. (d) Malisch, W.; Möller, S.; Fey, O.; Wekel, H.-U.; Pikl, R.; Posset, U.; Kiefer, W. J. Organomet. Chem. 1996, 507, 117-124. Malisch, W.; Lankat, R.; Seelbach, W.; Reising, J.; Noltemeyer, R.; Pikl, U.; Posset, U.; Kiefer, W. Chem. Ber. 1995, 128, 1109-1115.
9. (d) Malisch, W.; Möller, S.; Fey, O.; Wekel, H.-U.; Pikl, R.; Posset, U.; Kiefer, W. J. Organomet. Chem. 1996, 507, 117-124. Malisch, W.; Lankat, R.; Seelbach, W.; Reising, J.; Noltemeyer, R.; Pikl, U.; Posset, U.; Kiefer, W. Chem. Ber. 1995, 128, 1109-1115.
10. (e) Malisch, W.; Jehle, H.; Möller, S.; Thum, G.; Reising, J.; Gbureck, A.; Nagel, V.; Fickert, C.; Kiefer, W.; Nieger, M. Eur. J. Inorg. Chem. 1999, 1597-1605.
11. (a) Malisch, W.; Lankat, R.; Schmitzer, S.; Reising, J. Inorg. Chem. 1995, 34, 5701-5702.
12. (b) Malisch, W.; Jehle, H.; Möller, S.; Saha-Möller, C.; Adam, W. Eur. J. Inorg. Chem. 1998, 1585-1587.
13. Vahrenkamp, H.; Steiert, D.; Gusbeth, P. J. Organomet. Chem. 1981, 209, C17.
14. Aylett, B. J.; Campbell, J. M. J. Chem. Soc. A 1969, 2110.
15. Aylett, B. J.; Colquhoun, H. M. J. Chem. Res., Synop. 1977, 6, 148.
16. Abraham, K.; Urry, G. Inorg. Chem. 1973, 12, 2850-2856.
17. Hencken, G.; Weiss, E. Chem. Ber. 1973, 106, 1747.
18. Herrmann, W. A.; Voss, E.; Guggolz, E.; Ziegler, M. L. J. Organomet. Chem. 1985, 284, 47-57.
19. 2Si(Cl)H (3) see: Malisch, W.; Ries, W. Chem. Ber. 1979, 112, 1304-1315.
20. 2Si: C, 33.04; H, 2.18. Found: C, 32.68; H, 2.06. Mp: 86 °C dec.
21. 2Si: C, 35.44; H, 2.55. Found: C, 35.31; H, 2.43.
22. (a) Mitchell, T. N.; Marsmann, H. J. Organomet. Chem. 1978, 150, 171.
23. (b) Brinckmann, F. E.; Coyle, T. D. J. Phys. Chem. 1968, 72, 660.
24. max = 54°, T = 293 K, R1(I > 2σ(I)) = 0.028, wR2 = 0.032, GooF = 1.002 for 3011 reflections and 238 parameters.
25. Sheldrick, W. S. In The Chemistry of Organic Silicon Compounds; Patai, S., Rappoport, Z., Eds.; Wiley: New York, 1989.
26. 2 (5) is, to our knowledge, the first bis-metalated silane for which intermolecular bonding is described.
27. 3Si: C, 43.86; H, 3.40. Found: C, 43.42; H, 3.31.
28. 2). See: (a) Lin, Y. C.; Calabrese, J. C.; Wreford, S. S. J. Am. Chem. Soc. 1983, 105, 1679-1680.
29. (b) Davies, D. L.; Dyke, A. F.; Knox, S. A. R.; Morris, M. J. J. Organomet. Chem. 1981, 215, C30.
30. (a) Malisch, W.; Ries, W. Angew. Chem. 1978, 90, 140-141.
31. (b) Tobita, H.; Kawano, Y.; Ogino, H. Chem. Lett. 1989, 2155.
32. (c) Kawano, Y.; Tobita, H.; Ogino, H. Organometallics 1992, 11, 499.
33. (d) Luh, L.-S.; Wen, Y.-S.; Tobita, H.; Ogino, H. Bull. Chem. Soc. Jpn. 1997, 70, 2193-2200.
34. (e) Ogino, H.; Tobita, H. Adv. Organomet. Chem. 1998, 42, 223-290.
35. 19
36. 5Si (531.97): C, 45.16; H, 3.03. Found: C, 44.48; H, 3.16.
37. (a) Manning, A. R. J. Chem. Soc. A 1971, 2321-2325.
38. (b) Madach, T.; Vahrenkamp, H. Chem. Ber. 1980, 113, 2675-2685.
39. Malisch, W.; Vögler, M.; Schumacher, D.; Nieger, M. Organometallics, submitted for publication.