Synthesis and reactivity of silicon transition metal complexes, 43. - Iron and ruthenium fragment substituted disilanes C5R5(OC)2M-Si2X5 (R = H, Me; M = Fe, Ru; X = Cl, H): Synthesis, structural and Raman spectroscopic characterisation, DFT calculation

European Journal of Inorganic Chemistry

Volumn , Issue 9, 1999, Pages 1597-1605

  Malisch, Wolfgang ^a   Jehle, Heinrich ^a   Möller, Stephan ^a   Thum, Gerhard ^a   Reising, Joachim ^a   Gbureck, Axel ^a   Nagel, Volker ^a   Fickert, Claudia ^a   Kiefer, Wolfgang ^a   Nieger, Martin ^b  

^a UNIVERSITY OF WÜRZBURG   (Germany)

^b UNIVERSITY OF BONN   (Germany)

Author keywords

Density functional theory; Ligand exchange at silicon; Metallo disilanes; Raman spectroscopy; Transition metal effect

Indexed keywords

CHELATION; CHLORINE COMPOUNDS; DENSITY FUNCTIONAL THEORY; IRON COMPOUNDS; LITHIUM COMPOUNDS; METAL COMPLEXES; SILICON COMPOUNDS; SYNTHESIS (CHEMICAL); TRANSITION METALS; X RAY ANALYSIS;

DENSITY-FUNCTIONAL-THEORY; DFT CALCULATION; DISILANES; LIGAND EXCHANGE AT SILICON; LIGAND EXCHANGES; METALLO-DISILANE; RAMAN SPECTROSCOPIC; SPECTROSCOPIC CHARACTERIZATION; TRANSITION METAL EFFECT; TRANSITION-METAL COMPLEX;

RAMAN SPECTROSCOPY;

ALUMINUM; CARBON TETRACHLORIDE; HYDROGEN; IRON; LITHIUM; METAL COMPLEX; RUTHENIUM; SILANE; SILICON; SODIUM;

ARTICLE; CHLORINATION; INFRARED SPECTROSCOPY; MATHEMATICAL ANALYSIS; PROTON NUCLEAR MAGNETIC RESONANCE; RAMAN SPECTROMETRY; REACTION ANALYSIS; STRUCTURE ANALYSIS; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

EID: 0032831532     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/(sici)1099-0682(199909)1999:9<1597::aid-ejic1597>3.0.co;2-0     Document Type: Article

References (69)

1. [1a] W. Malisch, J. Organomet. Chem. 1972, 39, C28-C30.
2. [1b] W. Malisch, ibid 1974, 82, 185-199.
3. [2a] R. B. King, K. H. Pannell, Z. Naturforsch 1969, 24b, 262.
4. [2b] B. K. Nicholson, J. Simpson, J. Organomet. Chem. 1974, 72, 211-220.
5. [2c] L. Parkanyi, K. H. Pannell, C. Hernandez, J. Organomet. Chem. 1983, 252, 127-132.
6. [3a] K. H. Pannell, J. Cervantes, C. Hernandez, J. Cassias, S. Vincenti, Organometallics 1986, 5, 1056-1057.
7. [3b] K. H. Pannell, J. M. Rodzell Jr., C. Hernandez, J. Am. Chem. Soc. 1989, 111, 4482-4485.
8. [3c] H. Tobita, K. Ueno, H. Ogino, Chem. Lett. 1986, 1777-1780.
9. [3d] K. H. Pannell, S.-H. Lin, R. N. Kapoor, F. Cervantes-Lee, M. Pinon, L. Parkanyi, Organometallics 1990, 9, 2454-2462.
10. [3e] H. Tobita, K. Ueno, M. Shimoi, H. Ogino, J. Am. Chem. Soc. 1990, 112, 3415-3420.
11. [3f] T. Takeuchi, H. Tobita, H. Ogino, Organometallics 1991, 10, 835-836.
12. A. Haynes, M. W. George, M. T. Haward, M. Poliakoff, J. J. Turner, N. M. Boag, M. Green, J. Am. Chem. Soc. 1991, 113, 2011-2020.
13. [5a] B. Stadelmann, P. Lassacher, H. Stüger E. Hengge, J. Organomet. Chem. 1994, 482, 201-206.
14. [5b] M. J. Michalczyk, C. A. Recatto, J. C. Calabrese, M. J. Fink, J. Am. Chem. Soc. 1992, 114, 7955-7957.
15. W. Malisch, R. Lankat, W. Seelbach, J. Reising, M. Noltemeyer, R. Pikl, U. Posset, W. Kiefer, Chem. Ber. 1995, 128, 1109-1115.
16. 3a has already been mentioned in ref. [5] but yields are considerable lower (41%) in those experiments.
17. H.-U. Wekel, W. Malisch, J. Organomet. Chem. 1984, 264, C10-C13.
18. [9a] W. Jetz, W. A. G. Graham, J. Am. Chem. Soc. 1967, 89, 2773-2775.
19. [9b] U. Schubert, G. Kraft, E. Walther, Z. Anorg. Allg. Chem. 1984, 519, 96-106.
20. [10a] M. Schmeisser, P. Voss, Z. Anorg. Allg. Chem. 1964, 334, 50-56.
21. [10b] P. W. Schenk, H. Bloching, ibid 1964, 334, 57-65.
22. [10c] K. Hassler, E. Hengge, W. Raml, Monatshefte Chem. 1980, 111, 581-590.
23. [10d] H. E. O'Neal, M. A. Ring, W. H. Richardson, G. F. Licciardi, Organometallics 1989, 8, 1968-1973.
24. [10e] R. Becerra, H. M. Frey, B. P. Mason, R. Walsh, M. S. Gordon, J. Am. Chem. Soc. 1992, 114, 2751-2752.
25. [10f] R. Becerra, H. M. Frey, B. P. Mason, R. Walsh, J. Organomet. Chem. 1996, 527, 343-349.
26. [11a] A. Y. Vanderwielen, M. A. Ring, H. E. O'Neal, J. Am. Chem. Soc. 1975, 97, 993-998.
27. [11b] H. Bock, B. Solouki, G. Maier, Angew Chem. 1985, 97, 205-206; Angew. Chem. Int. Ed. Engl. 1985, 24, 205-206.
28. [11b] H. Bock, B. Solouki, G. Maier, Angew Chem. 1985, 97, 205-206; Angew. Chem. Int. Ed. Engl. 1985, 24, 205-206.
29. [11c] J. M. Coffin, T. P. Hamilton, P. Pulay, I. Hargittai, Inorg. Chem. 1989, 28, 4092-4094.
30. [11d] M. S. Gordon, W. Nelson, Organometallics 1995, 14, 1067-1069.
31. 29Si-NMR-Spectroscopic Results in NMR-Basic Principles and Progress, Springer, Berlin-Heidelberg-New York, 1981, Bd. 7, S. 65.
32. R. L. Scholl, G. E. Maciel, W. K. Musker, J. Am. Chem. Soc. 1972, 94, 6376-6385.
33. R. Loewer, M. Vongehr, H. C. Marsmann, Chem.-Ztg. 1975, 99, 33.
34. H. C. Marsmann, H. G. Horn, Z. Naturforsch. 1972, 27b, 1448-1451.
35. [16a] X. Zhou, C. J. M. Wheeless, R. Liu, Vibrational Spectroscopy 1996, 12, 53-63.
36. [16b] X. Zhou, R. Liu, Vibrational Spectroscopy 1996, 12, 65-71.
37. [16c] X. Zhou, S. J. Mole, R. Liu, Vibrational Spectroscopy 1996, 12, 73-79.
38. C. Fickert, PhD thesis, Würzburg, 1998.
39. P. Pulay, G. Fogarasi, G. Pongor, J. E. Boggs, A. Vargha, J. Am. Chem. Soc. 1983, 105, 7037-7047.
40. 5, the decomposition product of 3a.
41. S. Schmitzer, U. Weis, H. Käb, W. Buchner, W. Malisch, T. Polzer, U. Posset, W. Kiefer, Inorg. Chem. 1993, 32, 303-306.
42. [21a] W. Malisch, S. Möller, O. Fey, H.-U. Wekel, R. Pikl, U. Posset, W. Kiefer, J. Organomet. Chem. 1996, 507, 117-124.
43. [21b] W. Palitzsch, U. Bohme, G. Roewer, J. Organomet. Chem. 1997, 540, 83-88.
44. [21c] U. Schubert, G. Kraft, E. Walther, Z. Anorg. Allg. Chem. 1984, 519, 86.
45. [21d] R. West, E. K. Pham, J. Organomet. Chem. 1991, 402, 215.
46. [21e] L. Parkanyi, K. H. Pannell, C. Hernandez, J. Organomet. Chem. 1983, 252, 127.
47. [21f] T. J. Drahnak, R. West, J. C. Calabrese, J. Organomet. Chem. 1980, 198, 55.
48. [21g] W. Höhnle, H. G. von Schnering, Z. Anorg. Allg. Chem. 1980, 464, 139.
49. [21h] K. H. Pannell, S.-H. Lin, R. N. Kapoor, F. Cervantes-Lee, M. Pinon, E. Parkanyi, Organometallics 1990, 9, 2454-2462.
50. [21i] W. S. Sheldrick, in The Chemistry of Organic Silicon Compounds (Eds.: S. Patai, Z. Rappoport), John Wiley & Sons Ltd, New York, 1989, 227.
51. B. Beagly, J. J. Monaghan, J. Molec. Struct. 1971, 8, 401.-W. S. Sheldrick, in The Chemistry of Organic Silicon Compounds (Eds.: S. Patai, Z. Rappoport), John Wiley & Sons Ltd, New York, 1989.
52. B. Beagly, J. J. Monaghan, J. Molec. Struct. 1971, 8, 401.-W. S. Sheldrick, in The Chemistry of Organic Silicon Compounds (Eds.: S. Patai, Z. Rappoport), John Wiley & Sons Ltd, New York, 1989.
53. [23a] T. S. Piper, G. Wilkinson, J. Inorg. Nucl. Chem. 1956, 3, 104-124.
54. [23b] T. Blackmore, M. I. Bruce, F. G. A. Stone, J. Chem. Soc. (A) 1968, 2158-2162.
55. [24a] D. H. Gibson, W-L. Hsu, F. U. Ahmed, J. Organomet. Chem. 1981, 215, 379-401.
56. [24b] A. Stasunik, D. Wilson, W. Malisch, J. Organomet. Chem. 1984, 270, C18-C22.
57. [25a] G. M. Sheldrick, SHELXS-96, Program for Structure Solution, Göttingen 1996.
58. [25b] G. M. Sheldrick, SHELXL-96, Program for Structure Determination, Göttingen 1996.
59. Enraf.Nonius, Structure-Determination-Package, Enraf-Nonius, Delft, The Netherlands 1984.
60. M. J. Almond, A. J. Downs, in Spectroscopy of Matrix Isolated Species, Advances in Spectroscopy, (Eds.: R. J. H. Clark, R. E. Hester), Vol. 17, Wiley, Chichester, UK, 1989, p. 15.
61. D. Gernet, W. Kiefer, Fresenius J. Anal. Chem. 1998, 362, in press.
62. Gaussian94, Revision D 5, M. J. Frisch, G. W. Trucks, H. B. Schlegel, P. M. W. Gill, B. G. Johnson, M. A. Robb, J. R. Cheeseman, T. Keith, G. A. Petersson, J. A. Montgomery, K. Raghavachari, M. A. Al-Laham, V. G. Zakrzewski, J. V. Ortiz, J. B. Foresman, J. Cioslowski, B. B. Stefanov, A. Nanayakkara, M. Challacombe, C. Y. Peng, P. Y. Ayala, W. Chen, M. W. Wong, J. L. Andres, E. S. Replogle, R. Gomberts, R. L. Martin, D. J. Fox, J. S.Binkley, D. J. Defrees, J. Baker, J. P. Stewart, M. Heat-Gordon, C. Gonzalez, J. A. Pople, Gaussian, Inc., Pittsburgh PA, 1995.
63. A. Gbureck, R. Pikl, W. Kiefer, Asian J. Phys., submitted.
64. A. D. Becke, Phys. Rev. A 1988, 38, 3098.
65. J. P. Perdew, Y. Wang, Phys. Rev. B 1992, 45, 13244.
66. [33a] P. J. Hay, W. R. Wadt, J. Chem. Phys. 1985, 82, 270-283.
67. [33b] W. R. Wadt, P. J. Hay, J. Chem. Phys. 1985, 82, 284-298.
68. [33c] P. J. Hay, W. R. Wadt, J. Chem. Phys. 1985, 82, 299-310.
69. T. H. Dunning, Jr., P. J. Hay, in Modern Theoretical Chemistry, (Ed.: H. F. Schaefer), III, Plenum: New York, 1976, 1-28.