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Many naturally occurring surfaces, such as proteins and metal oxides, are amphoteric and undergo charge reversal over a wide pH range, due to protonation in acid and deprotonation or coordination of hydroxide. However these surfaces are not suitable for use as control elements in self-assembly because very large changes in pH are required to achieve charge reversal and because they are difficult to fabricate. The design of surfaces capable of switching hydrophobicity in response to changes in electrical potential was reported recently: Lahann, J.; Mitragotri, S.; Tran, T.-N.; Kaido, H.; Sundaram, J.; Choi, I. S.; Hoffer, S.; Somorjai, G. A.; Langer, R. Science 2003, 299, 371-374.
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0038504629
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note
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0038166057
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note
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1H NMR.; this reaction reaches completion in 7 days at 20 °C.
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19
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0038166013
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Scientific Computing International
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Film Wizard, 6.5.1 Scientific Computing International, 1999.
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Film Wizard, 6.5.1
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20
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3743134422
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-1) are typical of densely packed all-anti hydrocarbon chains. (Dubois, L. H.; Nuzzo, R. G. Annu. Rev. Phys. Chem. 1992, 43, 437-463.) If the layer is densely packed, it must be highly tilted to give the estimated area per molecule.
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22
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0038504628
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note
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12 and only varying the parameters of the dye thin film Lorentz functions. The simulation allows the absorbance of a free-standing film of dye to be calculated directly. Several sets of data at varying dye coverage for each dye were compared with simulated spectra, enabling correction factors to be calculated for the coverage obtained by direct integration of the spectra.
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23
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0038504626
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note
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4h symmetry with two oscillators and 150% for methylene blue, 1, with only one oscillator.
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24
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0038504627
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note
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Van der Waals footprint areas of molecules of dyes 1-3 were calculated using molecular mechanics (CaChe, 4.1, Oxford Molecular Ltd., 1999) and used to estimate monolayer coverages, assuming either flat or vertical orientations of the chromophores on the surface.
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25
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0000586223
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0035033813
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