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0038551471
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note
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- [DPPE = bis(diphenylphosphino)ethane] at 70 °C reached 70% completion after 2 h to form 3 in 21% GC yield. This reaction formed predominantly disilylated uncyclized material.
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26
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0001334715
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Trost, B. M., Fleming, I., Eds.; Pergamon: Oxford, UK
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29
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0037537303
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note
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2Et catalyzed by 2 at high and low silane concentration, respectively.
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30
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0037875133
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We thank a reviewer for alerting our attention to this inconsistency
-
We thank a reviewer for alerting our attention to this inconsistency.
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31
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0037875135
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note
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2t-Bu to rhodium due to unfavorable steric interaction may either preclude formation of the rhodium silyl hydride species I or prohibit reductive elimination from rhodium alkenyl intermediates II and III. In either case, cyclotrimerization presumably occurs in a reaction manifold separate from that which generates the silylated products.
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32
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0003184636
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