Kinetics of methane nonoxidative aromatization over Ru-Mo/HZSM-5 catalyst

Industrial and Engineering Chemistry Research

Volumn 42, Issue 14, 2003, Pages 3203-3209

  Iliuta, Maria C ^a   Iliuta, Ion ^a   Grandjean, Bernard P A ^a   Larachi, Faïçal ^a  

^a UNIVERSITÉ LAVAL   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORPTION; ATMOSPHERIC PRESSURE; CATALYSTS; DEHYDROGENATION; ENTHALPY; REACTION KINETICS;

DIFFERENTIAL REACTORS;

AROMATIC HYDROCARBONS;

METHANE; MOLYBDENUM; RUTHENIUM;

DEHYDROGENATION; ENTHALPY; ENTROPY; FIXED BED; KINETICS; METHANE; REACTOR;

ADSORPTION; AROMATIZATION; ARTICLE; ATMOSPHERIC PRESSURE; CATALYST; CHEMICAL REACTION; CHEMICAL REACTION KINETICS; DEHYDROGENATION; ENTHALPY; ENTROPY; FLOW RATE; FLUIDIZED BED REACTOR; REACTION ANALYSIS; REACTION TIME; TEMPERATURE; THERMODYNAMICS;

EID: 0038337858     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie030044r     Document Type: Article

References (35)

1. Xu, Y.; Lin, L. Recent Advances in Methane Dehydroaromatization over Transition Metal Ion-modified Zeolite Catalysts under Non-oxidative Conditions. Appl. Catal., A 1999, 188, 53.
2. Zhang, C.-L.; Li, S.; Yuan, Y.; Zhang, W.-X.; Wu, T.-H.; Lin, L.-W. Aromatization of Methane in the Absence of Oxygen over Mo-based Catalysts Supported on Different Types of Zeolites. Catal. Lett. 1998, 56, 207.
3. Weckhuysen, B. M.; Wang, D.; Rosynek, M. P.; Lunsford, J. H. Conversion of Methane to Benzene over Transition Metal Ion ZSM-5 Zeolites. I. Catalytic Characterization. J. Catal. 1998, 175, 338.
4. Solymosi, F.; Cserényi, A.; Szöke, A.; Bánsági, T.; Oszkó, A. Aromatization of Methane over Supported and Unsupported Mo-Based Catalysts. J. Catal. 1997, 165, 150.
5. Liu, W.; Xu, Y.; Wong, S.-T.; Wang, L.; Qiu, J.; Yang, N. Methane Dehydrogenation and Aromatization in the Absence of Oxygen on Mo/HZSM-5: A Study on the Interaction between Mo Species and HZSM-5 by using 27Al and 29Si MAS NMR. J. Mol. Catal., A 1997, 120, 257.
6. Wang, D.; Lunsford, J. H.; Rosynek, M. P. Catalytic Conversion of Methane to Benzene over Mo/ZSM-5. Top. Catal. 1996, 3, 289.
7. Xu, Y.; Liu, S.; Wang, L.; Xie, M.; Guo, X. Methane Activation without Using Oxidants over Mo/HZSM-5 Zeolite Catalysts. Catal. Lett. 1995, 30, 135.
8. Chen, L.; Lin, L.; Xu, Z.; Li, X.; Zhang, T. Dehydrooligomerization of Methane to Ethylene and Aromatics over Molybdenum/HZSM-5 Catalysts. J. Catal. 1995, 157, 190.
9. Wang, L.; Tao, L.; Xie, M.; Xu, G.; Huang, J.; Xu, Y. Dehydrogenation and Aromatization of Methane under Nonoxidizing Conditions. Catal. Lett. 1993, 21, 35.
10. Solymosi, F.; Erdöhelyi, A.; Szöke, A. Dehydrogenation of methane on supported molybdenum oxides. Formation of benzene from methane. Catal. Lett. 1995, 32, 43.
11. Liu, S.; Wang, L.; Ohnishi, R.; Ichikawa, M. Bifunctional Catalysts of Mo/HZSM-5 in the Dehydroaromatization of Methane to Benzene and Naphthalene XAFS/TG/DTA/MASS/FTIR Characterization and Supporting Effects. J. Catal. 1999, 181, 175.
12. Iliuta, M. C.; Larachi, F.; Grandjean, B. P. A.; Iliuta, I.; Sayari, A. Methane Nonoxidative Aromatization over Ru-Mo/HZSM-5 in a Membrane Catalytic Reactor. Ind. Eng. Chem. Res. 2002, 41, 2371.
13. Shu, Y.; Xu, Y.; Wong, S.-T.; Wang, L., Guo, X. Promotional Effect of Ru on the Dedrogenation and Aromatization of Methane in the Absence of Oxygen over Mo/HZSM-5 Catalysts. J. Catal. 1997, 170, 11.
14. Zeng, J. L.; Xiong, Z. T.; Zhang, H. B.; Lin, G. D.; Tsai, K. R. Nonoxidative Dehydrogenation and Aromatization of Methane over W/HZSM-5-based Catalysts. Catal. Lett. 1998, 53, 119.
15. Chen, L.; Lin, L.; Xu, Z.; Zhang, T.; Li, X. Promotional Effect of Pt on Non-oxidative Methane Transformation over Mo HZSM-5 Catalyst. Catal. Lett. 1996, 39, 169.
16. Tan, P.; Xu, Z.; Zhang, T.; Chen, L.; Lin, L. Aromatization of Methane over Different Mo-supported Catalysts in the Absence of Oxygen. React. Kinet. Catal. Lett. 1997, 61, 391.
17. Li, S.; Zhang, C.; Kan, Q.; Wang, D.; Wu, T.; Lin, L. The Function of Cu(II) Ions in the Mo/CuH-ZSM-5 Catalyst for Methane Conversion under Non-oxidative Conditions. Appl. Catal., A 1999, 187, 199.
18. Wang, L.; Xu, Y.; Wong, S.-T.; Cui, W.; Guo, X. Activity and Stability Enchancement of Mo/HZSM-5-based Catalysts for Methane Non-oxidative Transformation to Aromatics and C2 Hydrocarbons: Effect of Additives and Pretreatment Conditions. Appl. Catal., A 1997, 152, 173.
19. Liu, S.; Dong, Q.; Ohnishi, R.; Ichikawa, M. Remarkable Non-oxidative Conversion of Methane to Naphthalene and Benzene on Co and Fe Modified Mo/HZSM-5 Catalysts. Chem. Commun. 1997, 1455.
20. Iliuta, M. C.; Grandjean, B. P. A.; Larachi, F. Methane Nonoxidative Aromatization over Ru-Mo/HZSM-5 at Temperatures up to 973 Kin a Palladium-Silver/Stainless Steel Membrane Reactor. Ind. Eng. Chem. Res. 2003, 42, 323.
21. Rival, O.; Grandjean, B. P. A.; Guy, C.; Sayari, A.; Larachi, F. Oxygen-Free Methane Aromatization in a Catalytic Membrane Reactor. Ind. Eng. Chem. Res. 2001, 40, 2212.
22. 2C/ZSM-5 Catalysts. Catal. Lett. 1996, 39, 157.
23. Borry, R. W., III; Kim, Y. H.; Huffsmith, A.; Reimer, J. A.; Iglesia, E. Structure and Density of Mo and Acid Sites in Mo-Exchanged H-ZSM5 Cataysts for Nonoxidative Methane Conversion. J. Phys. Chem. B. 1999, 103, 5787.
24. Li, W.; Meitzner, G. D.; Borry, R. W.; Iglesia, E. Raman and X-Ray Absorption Studies of Mo Species in Mo/H - ZSM5 Catalysts for Non-Oxidative CH4 Reactions. J. Catal. 2000, 191, 373.
25. 4 Aromatization. J. Ind. Eng. Chem. 2000, 6, 72.
26. Kim, Y. H.; Borry, R. W.; Iglesia, E. Genesis of Methane Activation Sites in Mo-exchanged H-ZSM-5 Catalysts. Microporous Mesoporous Mater. 2000, 35, 495.
27. Ding, W.; Li, S.; Meitzner, G. D.; Iglesia, E. Methane conversion to aromatics on Mo/H-ZSM5: Structure of Molybdenum Species in Working Catalysts. J. Phys. Chem. B 2001, 105, 506.
28. Levenspiel, O. Chemical Reaction Engineering; John Wiley & Sons: New York, 1999.
29. Fogler, H. S. Elements of Chemical Reaction Engineering; Prentice Hall Int.: New York, 1992.
30. Carberry J. J. Chemical and catalytic reaction engineering; McGraw-Hill: New York, 1976.
31. Temkin, M. I. Kinetics of some industrial heterogeneous catalytic reactions. Adv. Catal. 1979, 28, 173.
32. Marquardt, D. W. An algorithm for least-squares estimation of nonlinear parameters. J. Soc. Ind. Appl. Math. 1963, 11, 471.
33. NIST. Chemical Thermodynamics Database Version 1.1, U.S. Department of Commerce, National Institute of Standards and Technology, Gaithesburg MD 20899, 1990.
34. Froment, G. F.; Bischoff, K. B. Chemical Reactor Analysis and Design, 2nd ed.; John Wiley & Sons: New York, 1990.
35. Boudart M.; Mears, D.; Vannice, M. A. In Congres International Chimie Industrielle. Ind. Chim. Belge 1967, 32, 281.