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20544433174
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note
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H-ZSM5 samples (0% Mo) were heated to higher temperatures (973 K) in order to ensure complete isotopic exchange.
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-
-
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18
-
-
20544450776
-
-
note
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27Al NMR signal, indicating that 1.0 s was sufficient to allow full relaxation of all Al spin states. In this case, the NMR signal peak area, integrated using Peakfit (Jandel Scientific), is proportional to the number of Al centers represented in that peak.
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19
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0038944664
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20544452251
-
-
note
-
Experiments using unheated lines overestimated the amount of carbon deposited on the catalyst because of condensation of naphthalene and heavier products in the gas transfer lines.
-
-
-
-
22
-
-
20544436420
-
-
note
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HP 6890 gas chromatograph (Hewlett-Packard) equipped with a Carboxen 1000 packed column (3.2 mm x 2 m, Supelco) connected to a thermal conductivity detector and with a HP-1 capillary column (methyl silicone, 0.32 mm x 50 m x 1.05 mm, Hewlett-Packard) connected to a flame ionization detector.
-
-
-
-
23
-
-
20544442457
-
-
note
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All gases were >99.99% purity (from Praxair and Matheson) and were passed through molecular sieve (13X and 5A) traps before use. Flow rates were metered using electronic mass flow controllers (Porter Instruments).
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-
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24
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0008141970
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Imelik, B., Ed.; Elsevier Scientific Publishing Co.: Amsterdam
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-
-
20544467896
-
-
note
-
The initial concentration of Mo for this sample was 4.0 wt %, but after temperature-programmed treatment in air up to 973 K the sample contained 3.6 wt % Mo (Table 3).
-
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26
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0000730342
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-
-
20544453008
-
-
note
-
The initial Mo concentration for this sample was 8 wt %, but after temperature-programmed treatment in air the sample contained 6.3 wt % Mo (Table 3).
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28
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58149363184
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20544457536
-
-
note
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2O.
-
-
-
-
30
-
-
20544466642
-
-
note
-
2(g)/O(s)-D exchange were used for Mo-containing samples in the calculations shown in Table 4, because this led to a more accurate hydrogen atom balance.
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31
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0000622624
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20544434955
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Solymosi, F.1
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-
-
20544448443
-
-
note
-
3 vapor exchange preparation (Figure 6) results in only 4.3 wt % Mo, which is much less than expected if the external ZSM5 surface area was covered and framework OH groups were exchanged with Mo.
-
-
-
-
38
-
-
85088082529
-
-
note
-
3 may eventually spread into a monolayer, but below 773 K the weak bonds between bilayers are more likely to break than the strong Mo-O-Mo bonds within bilayers.
-
-
-
-
39
-
-
85088080388
-
-
note
-
2/g for a monolayer.
-
-
-
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40
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4344607102
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Heteropoly and hopoly Oxometalates
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Jorgensen, C. K., Ed.; Springer-Verlag: Berlin
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Pope, M.T.1
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85088082631
-
-
note
-
2 is 940 K, so mobility of ions in the O-Si-O lattice of ZSM5 should occur between 673 and 973 K.
-
-
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45
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0000815057
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Xu, Y.; Liu, W.; Wong, S.-T.; Wang, L.; Guo, X. Catal. Lett. 1996, 40, 207.
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