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Volumn 44, Issue 32, 2003, Pages 6095-6098

Formation of keto-carbeniums from 1,2,2-triarylacenaphthen-1-ols by breaking a long C-C bond: Unusual alcohol protonolysis accompanied by formal hydride abstraction

Author keywords

Dye; Electron transfer; Long bond; peri interaction; Protonolysis

Indexed keywords

ACENAPHTHENE DERIVATIVE; ALCOHOL DERIVATIVE; BASE; CARBENOID; FLUORINE DERIVATIVE; LEWIS ACID; NAPHTHALENE DERIVATIVE;

EID: 0038305195     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(03)01459-X     Document Type: Article
Times cited : (15)

References (33)
  • 14
    • 85031160780 scopus 로고    scopus 로고
    • note
    • -1 1614.
  • 16
    • 85031147030 scopus 로고    scopus 로고
    • note
    • -1, T=153 K. The final R value is 0.062 for 3510 independent reflections with I >3σI and 361 parameters.
  • 18
    • 85031157992 scopus 로고    scopus 로고
    • note
    • -1. Dimethylaniline undergoes irreversible oxidation at +0.72 V under the same conditions.
  • 33
    • 85031151001 scopus 로고    scopus 로고
    • note
    • + obeys the similar kinetics under Ar and under air, suggesting that oxygen does not play an important role in this reaction.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.