Adjacent-versus remote-site electron injection in TiO2 surfaces modified with binuclear ruthenium complexes

Inorganic Chemistry

Volumn 42, Issue 9, 2003, Pages 2919-2932

  Gholamkhass, Bobak ^a,b   Koike, Kazuhide ^a   Negishi, Nobuaki ^a   Hori, Hisao ^a   Sano, Taizo ^a   Takeuchi, Koji ^a  

^a NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY AIST   (Japan)

^b TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

1,4 BIS(1,10 PHENANTHROLINE[5,6 D]IMIDAZOL 2 YL)BENZENE; 2,2' BIPYRIDINE; 4,4' DICARBOXY 2,2' BIPYRIDINE; BENZENE DERIVATIVE; BIPYRIDINE DERIVATIVE; INDIUM TIN OXIDE; PHENAZINE DERIVATIVE; RUTHENIUM COMPLEX; TETRAPYRIDO[3,2 A:2',3' C:3'',2'' H:2''',3''' J]PHENAZINE DERIVATIVE; TIN DERIVATIVE; TITANIUM DIOXIDE; UNCLASSIFIED DRUG;

ADSORPTION; ARTICLE; CHEMICAL MODIFICATION; COMPLEX FORMATION; CRYSTAL STRUCTURE; ELECTRON TRANSPORT; ENERGY TRANSFER; FILM; LIGAND BINDING; METAL BINDING; MOLECULAR DYNAMICS; NANOTECHNOLOGY; PHOTOACTIVATION; RIGIDITY; SEMICONDUCTOR; SPECIES IDENTIFICATION; SURFACE PROPERTY;

EID: 0038297254     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic0341237     Document Type: Article

References (73)

1. (a) Desilvestro, J.; Grätzel, M.; Kavan, L.; Moser, J.; Augustynski, J. J. Am. Chem. Soc. 1985, 107, 2988.
2. (b) O'Regan, B.; Grätzel, M. Nature 1991, 353, 737.
3. (c) Amadelli, R.; Argazzi, R.; Bignozzi, C. A.; Scandola, F. J. Am. Chem. Soc. 1990, 112, 7099.
4. (d) Argazzi, R.; Bignozzi, C. A.; Heimer, T. A.; Castellano, F. N.; Meyer, G. J. J. Phys. Chem. B 1997, 101, 2591.
5. (e) Kamat, P. V. Prog. Inorg. Chem. 1996, 44, 273.
6. (a) Huang, S. Y.; Schlichthorl, G.; Nozik, A.; Grätzel, M.; Frank, A. J. J. Phys. Chem. B 1997, 101, 2576.
7. (b) Papageorgiou, P.; Barbé, C.; Grätzel, M. J. Phys. Chem. B 1998, 102, 4156.
8. (c) Dloczik, L.; Ileperuma, O.; Lauermann, I.; Peter, L. M.; Ponomarev, E. A.; Redmond, G.; Shaw, N. J.; Uhlendorf, I. J. Phys. Chem. B 1997, 101, 10281.
9. (d) Sayama, K.; Sugihara, H.; Arakawa, H. Chem. Mater. 1998, 10, 3825.
10. (e) Nazeeruddin, Md. K.; Zakeeruddin, S. M.; HumphryBaker, R.; Jirousek, M.; Liska, P.; Vlachopoulos, N.; Shklover, V.; Fischer, C.-H.; Grätzel, M. Inorg. Chem. 1999, 38, 6298.
11. (a) Comprehensive Supramolecular Photochemistry; Atwood, J. L., MacNicol, D. D., Davies, J. E. D., Vögtle, F., Eds.; Pergamon/ Elsevier: Oxford, 1996.
12. (b) Steed, J. W.; Atwood, J. L. Supramolecular Chemistry; John Wiley & Sons: West Sussex, U.K., 2000.
13. (c) Balzani, V.; Juris, A.; Venturi, M.; Campagna, S.; Serroni, S. Chem. Rev. 1996, 96, 759.
14. (a) Kleverlaan, C. J.; Indelli, M. T.; Bignozzi, C. A.; Pavanin, L.; Scandola, F.; Hasselman, G. M.; Meyer, G. J. J. Am. Chem. Soc. 2000, 122, 2840.
15. (b) Kleverlaan, C. J.; Alebbi, M.; Argazzi, R.; Bignozzi, C. A.; Hasselman, G. M.; Meyer, G. J. Inorg. Chem. 2000, 39, 1342.
16. (c) Treadway, J. A.; Moss, J. A.; Meyer, T. J. Inorg. Chem. 1999, 38, 4386.
17. (d) Argazzi, R.; Bignozzi, C. A.; Heimer, T. A.; Meyer, G. J. Inorg. Chem. 1997, 36, 2.
18. (e) Nazeeruddin, M. K.; Humphry-Baker, R.; Grätzel, M.; Murrer, B. A. Chem. Commun. 1998, 719.
19. +. See, for example: (a) Bonhôte, P.; Moser, J.-E.; Humphry-Baker, R.; Vlachopoulos, N.; Zakeeruddin, S. M.; Walder, L.; Grätzel, M. J. Am. Chem. Soc. 1999, 121, 1324. (b) Merrins, A.; Kleverlaan, C.; Will, G.; Rao, S. N.; Scandola, F.; Fitzmaurice, D. J. Phys. Chem. B 2001, 105, 2998. (c) Argazzi, R.; Bignozzi, C. A.; Heimer, T. A.; Castellano, F. N.; Meyer, G. J. J. Am. Chem. Soc. 1995, 117, 11815.
20. +. See, for example: (a) Bonhôte, P.; Moser, J.-E.; Humphry-Baker, R.; Vlachopoulos, N.; Zakeeruddin, S. M.; Walder, L.; Grätzel, M. J. Am. Chem. Soc. 1999, 121, 1324. (b) Merrins, A.; Kleverlaan, C.; Will, G.; Rao, S. N.; Scandola, F.; Fitzmaurice, D. J. Phys. Chem. B 2001, 105, 2998. (c) Argazzi, R.; Bignozzi, C. A.; Heimer, T. A.; Castellano, F. N.; Meyer, G. J. J. Am. Chem. Soc. 1995, 117, 11815.
21. +. See, for example: (a) Bonhôte, P.; Moser, J.-E.; Humphry-Baker, R.; Vlachopoulos, N.; Zakeeruddin, S. M.; Walder, L.; Grätzel, M. J. Am. Chem. Soc. 1999, 121, 1324. (b) Merrins, A.; Kleverlaan, C.; Will, G.; Rao, S. N.; Scandola, F.; Fitzmaurice, D. J. Phys. Chem. B 2001, 105, 2998. (c) Argazzi, R.; Bignozzi, C. A.; Heimer, T. A.; Castellano, F. N.; Meyer, G. J. J. Am. Chem. Soc. 1995, 117, 11815.
22. Subscripts "a" and "d" are used to indicate that S acts as an electron donor in some processes and as an electron acceptor in other processes.
23. See, for example: (a) Balzani, V.; Campagna, S.; Denti, G.; Juris, A.; Serroni, S.; Venturi, M. Acc. Chem. Res. 1998, 31, 26.
24. (b) Prathapan, S.; Johnson, T. E.; Lindsey, J. S. J. Am. Chem. Soc. 1993, 115, 7519.
25. (c) Gilat, S. L.; Kawai, S. H.; Lehn, J.-M. J. Chem. Soc., Chem. Commun. 1993, 1439.
26. (d) Credi, A., Balzani, V.; Langford, S. J.; Stoddart, J. F. J. Am. Chem. Soc. 1997, 119, 2679.
27. (e) Sauvage, J.-P.; Collin, J.-P.; Chambron, J.-C.; Guillerez. S.; Coudret, C.; Balzani, V.; Barigelletti, F.; De Cola, L.; Flamigni, L. Chem. Rev. 1994, 94, 993.
28. (a) Bolger, J.; Gourdon, A.: Ishow, E.; Launay, J.-P. Inorg. Chem. 1996, 35, 2937.
29. (b) Chiorboli, C.; Bignozzi, C. A.; Scandola, F.; Ishow, E.; Gourdon, A.; Launay, J.-P. Inorg. Chem. 1999, 38, 2402.
30. Chao, H.; Ye, B.-H.; Zhang, Q.-L.; Ji, L.-N. Inorg. Chem. Commun. 1999, 2, 338.
31. (a) Striplin, D. R.; Wall, C. G.; Erickson, B. W.; Meyer, T. J. J. Phys. Chem. B 1998, 102, 2383.
32. (b) Nazeeruddin, M. K.; Kay, A.; Rodicio, I.; Humphry-Baker, R.; Muller, E.; Liska, P.; Vlachopoulos, N.; Grätzel, M. J. Am. Chem. Soc. 1993, 115, 6382.
33. (c) Hou, Y.; Xe, P.; Zhang, B.; Cao, Y.; Xiao, X.; Wang, W. Inorg. Chem. 1999, 38, 6320.
34. We use the prefix "hetero" to indicate an unsymmetrical arrangement of the remote ligands, bpy and dcb, around the Ru atoms in the binuclear complexes.
35. Gholamkhass, B.; Koike, K.; Negishi, N.; Hori, H.; Takeuchi, K. Inorg. Chem. 2001, 40, 756.
36. Amouyal, E.; Homsi, A.; Chambron, J.-C.; Sauvage, J.-P. J. Chem. Soc., Dalton Trans. 1990, 1841.
37. Sullivan, B. P.; Meyer, T. J. Inorg. Chem. 1978, 17, 3334.
38. Goss, C. A.; Abruna, H. D. Inorg. Chem. 1985, 24, 4263.
39. Evans, I. P.; Spencer, A.; Wilkinson, G. J. Chem. Soc., Dalton Trans. 1973, 204.
40. Zakeeruddin, S. M.; Nazeeruddin, M. K.; Humphry-Baker, R.; Grätzel, M.; Shklover, V. Inorg. Chem. 1998, 37, 5251.
41. Meyer, T. J.; Meyer, G. J.; Pfenning, B. W.; Schoonover, J. R.; Timpson, C. J.; Wall, J. F.; Kobusch, C.; Chen, X.; Peek, B. M.; Wall, C. G.; Ou, W.; Erickson, B. W.; Bignozzi, C. A. Inorg. Chem. 1994, 33, 3952.
42. 2.
43. (a) Meyer, T. J. Pure Appl. Chem. 1986, 58, 1193.
44. (b) Juris, A.; Balzani, V.; Barigelletti, F.; Campagna, S.; Belser, P.; von Zelewsky, A. Coord. Chem. Rev. 1988, 84, 85.
45. (c) Vlcek, A. A.; Dosdworth, E. S.; Pietro, W. J.; Lever, A. B. P. Inorg. Chem. 1995, 34, 1906.
46. (d) Barigelletti, F.; Juris, A.; Balzani, V.; Belser, P.; von Zelewsky, A. Inorg. Chem. 1987, 26, 4115.
47. Kalyanasundaram, K. Photochemistry of Polypyridine and Porphyrin Complexes: Academic Press: San Diego, CA, 1992.
48. (a) Hammarström, L.; Barigelletti, F.; Flamigni, L.; Indelli, M. T.; Armaroli, N.; Calogero, G.; Guardigli, M.; Sour, A.; Collin, J.-P.; Sauvage, J.-P. J. Phys. Chem. A 1997, 101, 9061.
49. (b )Collin, J.-P.; Lainé, P.; Launay, J.-P.; Sauvage, J.-P.; Sour, A. J. Chem. Soc., Chem. Commun. 1993, 434.
50. Kober, E. M.; Caspar, J. V.; Sullivan, B. P.; Meyer, T. J. Inorg. Chem. 1988, 27, 4587.
51. (a) Caspar, J. V.; Meyer, T. J. Inorg. Chem, 1983, 22, 2444.
52. (b) Kober, E. M.; Caspar, J. V.; Lumpkin, R. S.; Meyer, T. J. J. Phys. Chem. 1986, 90, 3722.
53. (c) Barkawi, K. R.; Murtaza, Z.; Meyer, T. J. J. Phys. Chem. 1991, 95, 97.
54. (d) Omberg, K. M.; Schoonover, J. R.; Treadway, J. A.; Leasure, R. M.; Dyer, R. B.; Meyer, T. J. J. Am. Chem. Soc. 1997, 119, 7013.
55. -1.
56. 2 films from that of the sensitized films.
57. 18 Thus, the calculated HVSCs are 2.4 and 2.1 for the bfimbz and tpphz systems, respectively.
58. 2 surface only through two carboxylic functional groups located on one dcb, allowing the molecule to adjust its spatial conformation, with respect to the surface. However, the rigidity of the BL still prevents bending along the Ru-Ru axis.
59. Trammell, S. A.; Moss, J. A.; Yang, J. C.; Nakhle, B. M.; Slate, C. A.; Odobel, F.; Sykora, M.; Erickson, B. W.; Meyer, T. J. Inorg. Chem. 1999, 38, 3665.
60. (a) Braterman, P. S.; Harriman, A.; Heath, G. A.; Yellowless, L. J. Chem. Soc., Dalton Trans. 1983, 1801.
61. (b) Gholamkhass, B.; Nozaki, K.; Ohno, T. J. Phys. Chem. B 1997, 101, 9010.
62. Fujita, M.; Ishida, A.; Majima, T.; Takamuku, S. J. Phys. Chem. 1996, 100, 5382.
63. Gholamkhass, B. Ph.D. Dissertation, Osaka University, Osaka, Japan, 1998.
64. 4+, peaks at 350 and 370 nm were shifted to 363 and 383 nm, respectively. Details are reported in ref 31.
65. 3MLCT excited state of the binuclear complexes were obtained by assuming 100%-efficient energy transfer to anthracene. Details are reported in: Ohno, T.; Yoshimura, A.; Mataga, N. J. Phys. Chem, 1990, 94, 4871.
66. Rothenberger, G.; Fitzmaurice, D.; Grätzel, M. J. Phys. Chem. 1992, 96, 5983.
67. 1/amd (a = b = 3.7852 Å, c = 9,5139 Å, α = β = γ = 90%), and lattice boundaries of 4, 1, and 3 in the a-, b-, and c-directions, respectively.
68. For homobinuclear complexes, deposition of the dye molecule on the surface through four ester bonds has led to deformation of the bpy planar structure. Therefore, only three ester bonds were formed to deposit the molecule.
69. 29b in both the former and latter. Close examination of transient spectra in Figure 5a shows that the absorption band at λ < 400 nm peaks well below 370 nm.
70. The approximate energies are estimated on the basis of electrochemical measurements in solution.
71. -).
72. Lees, A. C.; Kleverlaan, C. J.; Bignozzi, C. A.; Vos, J. G. Inorg. Chem. 2001, 40, 5343.
73. Tachibana, Y.; Moser, J. E.; Grätzel, M.; Klug, D. R.; Durrant, J. R. J. Phys. Chem. 1996, 100, 20056.