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Volumn 42, Issue 10, 2003, Pages 3199-3207

Synthesis of mono- and dihalogenated derivatives of (Me2S)2B12H10 and palladium-catalyzed boron-carbon cross-coupling reactions of the iodides with grignard reagents

Author keywords

[No Author keywords available]

Indexed keywords

BORANE DERIVATIVE; BORON DERIVATIVE; BROMIDE; CARBON; CHLORIDE; HALOGEN; IODIDE; MAGNESIUM DERIVATIVE; PALLADIUM COMPLEX; REAGENT; SELENIUM DERIVATIVE;

EID: 0038291822     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic020600u     Document Type: Article
Times cited : (27)

References (34)
  • 1
    • 0003397781 scopus 로고    scopus 로고
    • Diederich, F., Stang, P. J., Eds.; Wiley-VCH: Weinheim, Germany
    • Metal-Catalyzed Cross-Coupling Reactions; Diederich, F., Stang, P. J., Eds.; Wiley-VCH: Weinheim, Germany. 1998.
    • (1998) Metal-Catalyzed Cross-Coupling Reactions
  • 21
    • 0038367026 scopus 로고    scopus 로고
    • Larsson, B., Crawford, J., Weinreich, R., Eds.; Elsevier: New York
    • (a) Schaffer, S.; Gabel, D. In Advances in Neutron Capture Therapy; Larsson, B., Crawford, J., Weinreich, R., Eds.; Elsevier: New York, 1997; Vol. II, pp 38-41.
    • (1997) Advances in Neutron Capture Therapy , vol.2 , pp. 38-41
    • Schaffer, S.1    Gabel, D.2
  • 25
    • 0010802162 scopus 로고    scopus 로고
    • Siebert, W.; Ed.; The Royal Society of Chemistry: Cambridge, U.K.
    • (b) Morris, J. H.; Brattsev, V. A.; Gaines, D. F. In Advances In Boron Chemistry; Siebert, W.; Ed.; The Royal Society of Chemistry: Cambridge, U.K., 1997; pp 434-437.
    • (1997) Advances in Boron Chemistry , pp. 434-437
    • Morris, J.H.1    Brattsev, V.A.2    Gaines, D.F.3
  • 27
    • 0038028871 scopus 로고    scopus 로고
    • note
    • 11B NMR of the same solution. It was concluded that the equilibrium constant for the oxidative addition of the carboranyl boron-iodine bond to a zerovalent palladium is very unfavorable.
  • 32
    • 0004150157 scopus 로고    scopus 로고
    • Bruker Analytical X-ray Systems: Madison, WI
    • SHELXTL, version 5.10; Bruker Analytical X-ray Systems: Madison, WI, 1997.
    • (1997) SHELXTL, Version 5.10
  • 33
    • 0038028872 scopus 로고    scopus 로고
    • note
    • Although the procedure below uses 4 as a starting material, 5 can be prepared directly from 2 using 2 equiv of bromine.
  • 34
    • 0038705350 scopus 로고
    • Bromine-dimethyl sulfide complex is used in this procedure solely due to the convenience of handling a solid reagent. For its preparation see Olah, G. A.; Vankar, Y. D.; Arvanaghi, M.; Prakash, G. K. S. Synthesis 1979, 701-721. Bromine can be used instead as described above for the synthesis of 4.
    • (1979) Synthesis , pp. 701-721
    • Olah, G.A.1    Vankar, Y.D.2    Arvanaghi, M.3    Prakash, G.K.S.4


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.