메뉴 건너뛰기




Volumn 107, Issue 20, 2003, Pages 4130-4135

Effects of substituents on arsenic-tin triple bonds: A theoretical study

Author keywords

[No Author keywords available]

Indexed keywords

ELECTRONEGATIVITY; POTENTIAL ENERGY SURFACE; TRIPLE BONDS; UNIMOLECULAR REARRANGEMENT;

EID: 0038281437     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp022236q     Document Type: Article
Times cited : (10)

References (54)
  • 2
    • 0038068697 scopus 로고
    • Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon: New York; Chapter 6
    • (b) Davies, A. G. Comprehensive Organometallic Chemistry II; Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon: New York, 1995; Chapter 6.
    • (1995) Comprehensive Organometallic Chemistry II
    • Davies, A.G.1
  • 17
    • 0038407055 scopus 로고
    • Abel, E. W., Stone, F. G. A., Wilkinson, G. Eds.; Pergamon: New York; Chapter 8
    • (b) Wardell, J. L. Comprehensive Organometallic Chemistry II; Abel, E. W., Stone, F. G. A., Wilkinson, G. Eds.; Pergamon: New York, 1995; Chapter 8.
    • (1995) Comprehensive Organometallic Chemistry II
    • Wardell, J.L.1
  • 20
  • 33
    • 0004142031 scopus 로고    scopus 로고
    • Houghton Mifflin Company: New York; Chapter 18
    • Zumdahl, S. S.; Zumdahl, A. S. Chemistry; Houghton Mifflin Company: New York, 2000; Chapter 18.
    • (2000) Chemistry
    • Zumdahl, S.S.1    Zumdahl, A.S.2
  • 37
    • 0038745163 scopus 로고    scopus 로고
    • note
    • It is likely that some of the trends that are revealed are influenced by the relativistic contributions from the "heavy" species. The major relativistic effects for the As and Sn elements were incorporated into the ECPs we used. However, to examine the influence of the relativistic effects on a given molecular property, it is necessary to compare results of relativistic (R) and nonrelativistic (NR) calculations on the property (e.g., ref 15). We believe that an analysis of this type provides more insight into the periodic trends revealed and discussed in this work. Examples of the comparative NR and R calculations on the group 15 compounds can be found in the recent literature (e.g., ref 16).
  • 38
    • 0038745166 scopus 로고    scopus 로고
    • note
    • The necessity of the relativistic effects for the elucidation of the As-Sn bond was suggested by a reviewer.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.