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Volumn 15, Issue 21, 1996, Pages 4346-4348

Formation of novel trinuclear μ3-s-cis-η2:η2-1,3-diene complexes of ruthenium having an agostic Ru-H-C interaction. Direct evidence for diene activation in cooperation with the three metal centers

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Indexed keywords


EID: 0001182847     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om9602466     Document Type: Article
Times cited : (30)

References (45)
  • 25
    • 5344248926 scopus 로고    scopus 로고
    • note
    • Experimental details for 4: A 50-mL Schlenk tube was charged with 0.400 g (0.56 mmol) of 1 and 20 mL of toluene. The Schlenk tube was evacuated after the solvent was frozen by using liquid nitrogen. Then the solution was warmed to room temperature, and a rubber balloon filled with 1 atm of butadiene was connected to the Schlenk tube. The mixture was stirred at room temperature for 14 h. Removal of the solvent under reduced pressure followed by purification by column chromatography on alumina with toluene/THF (20/1) afforded 0.300 g (70%) of 4 as a dark-green crystalline solid. Recrystallization from pentane gave dark-green prisms.
  • 39
    • 5344279362 scopus 로고    scopus 로고
    • note
    • w = 0.044.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.