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Experimental details for 4: A 50-mL Schlenk tube was charged with 0.400 g (0.56 mmol) of 1 and 20 mL of toluene. The Schlenk tube was evacuated after the solvent was frozen by using liquid nitrogen. Then the solution was warmed to room temperature, and a rubber balloon filled with 1 atm of butadiene was connected to the Schlenk tube. The mixture was stirred at room temperature for 14 h. Removal of the solvent under reduced pressure followed by purification by column chromatography on alumina with toluene/THF (20/1) afforded 0.300 g (70%) of 4 as a dark-green crystalline solid. Recrystallization from pentane gave dark-green prisms.
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w = 0.044.
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