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0037945055
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note
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2 fragments on the left and right sides of the reactions equation and the free and bonded forms of cod should be almost equal. The contributions which are evoked by different conformations of the substituents R in the free and complex forms of the phosphines are difficult to evaluate. However, as we discussed above, we have no indication of any unfavorable steric interactions of the BABAR-Phos ligands in the coordination sphere of 3. Furthermore, BABAR-Phos molecules have a very rigid structure, which does not change much upon complexation. This can be shown by the comparison between a number of related BABAR-Phos ligands and their complexes, whose structures we determined by X-ray analyses (Liedtke, J. ETH-Dissertation No. 13688, 2000). Therefore, it can be assumed that the small enthalpy reported here is mainly due to a low Pt-P binding energy.
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