Substitution reactions on cyclometallated Pt(IV) complexes; a kinetic survey of the bond strength of Pt-S, N, and P-based ligands

Inorganica Chimica Acta

Volumn 351, Issue 1, 2003, Pages 269-277

  Esteban, Julio ^a   Font Bardia, Mercè ^a   Gallego, Carlos ^a   González, Gabriel ^a   Martínez, Manuel ^a   Solans, Xavier ^a  

^a UNIVERSITY OF BARCELONA   (Spain)

Author keywords

Kinetics; Pt(IV) complexes; Solvent; Substitutions

Indexed keywords

CHLORINE COMPOUNDS; DISSOCIATION; ENZYME KINETICS; EQUILIBRIUM CONSTANTS; HYDROGEN BONDS; LIGANDS; NITROGEN; PHOSPHORUS; RATE CONSTANTS; SOLVENTS; SUBSTITUTION REACTIONS; SULFUR;

CHLORIDE LIGANDS; DISSOCIATIVE MECHANISMS; GEOMETRICAL ARRANGEMENTS; LEAVING LIGAND; NITROGEN AND PHOSPHORUS; PHOSPHORUS DONOR; RATE DETERMINING STEP; RELATIVE VALUE;

PLATINUM COMPOUNDS;

ACETONE; ACID; CHLORIDE; CHLOROFORM; IMINE; LIGAND; METHYL GROUP; NITROGEN DERIVATIVE; PHOSPHORUS DERIVATIVE; PLATINUM DERIVATIVE; SOLVENT; SULFUR DERIVATIVE; TOLUENE;

ARTICLE; CHEMICAL BOND; CHEMICAL STRUCTURE; DISSOCIATION; ELECTRONICS; GEOMETRY; HYDROGEN BOND; MOLECULAR DYNAMICS; STEREOSPECIFICITY; STRUCTURE ANALYSIS; SUBSTITUTION REACTION; TEMPERATURE;

EID: 0038108701     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0020-1693(03)00117-8     Document Type: Article

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