Unexpected formal aryl insertion in a cyclometalated diphenylplatinum (IV) complex: The first seven-membered cyclometalated platinum compound structurally characterized

Organometallics

Volumn 21, Issue 16, 2002, Pages 3305-3307

  Font Bardía, Mercè ^a   Gallego, Carlos ^a   Martinez, Manuel ^a   Solans, Xavier ^a  

^a UNIVERSITY OF BARCELONA   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

AROMATIC COMPOUNDS; CHEMICAL BONDS; COMPLEXATION; COORDINATION REACTIONS; CRYSTAL STRUCTURE; DERIVATIVES; DISSOCIATION; MOLECULAR STRUCTURE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PLATINUM COMPOUNDS; SUBSTITUTION REACTIONS; X RAY ANALYSIS;

CYCLOMETALATION; ELIMINATION REACTIONS;

ORGANOMETALLICS;

EID: 0038826992     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om020260k     Document Type: Article

References (24)

1. (a) Tobe, M. L.; Burgess, J. Inorganic Reaction Mechanisms; Longmans Green: London, 1999.
2. (b) de Vito, D.; Sidorenkova, H.; Rotzinger, F. P.; Weber, J.; Merbach, A. E. Inorg. Chem. 2000, 39, 5547.
3. Parshall, G. W.; Ittle, S. D. Homogeneous Catalysis, 2nd ed.; Wiley: New York, 1992.
4. Puddephatt, R. J. Angew. Chem., Int. Ed. 2002, 41, 261.
5. (a) Bernhardt, P. V.; Gallego, C.; Martinez, M. Organometallics 2000, 19, 4862.
6. (b) Bernhardt, P. V.; Gallego, C.; Martinez, M.; Parella, T. Inorg. Chem. 2002, 41, 1471.
7. (a) Crespo, M.; Martinez, M.; Sales, J. Organometallics 1993, 12, 4267.
8. (b) Crespo, M.; Martinez, M.; Sales, J.; Solans, X.; Font-Bardía, M. Organometallics 1992, 11, 1288.
9. 2) - 0.1447 (all data).
10. (a) Crumpton, D. M.; Goldberg, K. I. J. Am. Chem. Soc. 2000, 122, 962.
11. (b) Barlett, K. L.; Goldberg, K. I.; Borden, W. T. Organometallics 2000, 20, 2669.
12. (c) Puddephatt, R. J. Coord. Chem. Rev. 2001, 219-221, 157.
13. 2) = 0.0786 (all data).
14. Crespo, M.; Font-Bardía, M.; Solans, X. Polyhedron 2002, 21, 105.
15. 2 added.
16. (a) Stang, P. J.; Zhong, Z.; Arif, A. M. Organometallics 1992, 1, 1017.
17. (b) Kayaki, Y.; Tsukamoto, H.; Kaneko, M.; Shimizu, I.; Yamamoto, A.; Tachikawa, M.; Nakajima, T. J. Organomet. Chem. 2001, 622, 199.
18. (a) de Felice, V.; de Renzi, A.; Tesauro, D.; Vitagliano, A.; Organometallics 1992, 11, 3669.
19. (b) Bergamini, P.; Costa, E.; Orpen, A. G.; Pringle, P. G.; Smith, M. B. Organometallics 1995, 14, 3178.
20. (c) Yagyu, T.; Suzaki, Y.; Osakada, K. Organometallics 2002, 21, 2088.
21. Reinarzt, S.; White, P. S.; Brookhart, M.; Templeton, J. L. J. Am. Chem. Soc. 2001, 123, 12724.
22. Fan, Y.; Hall, M. B. J. Chem. Soc., Dalton Trans. 2002, 713.
23. Puddephatt, R. J. Angew. Chem., Int. Ed. 2002, 41, 261.
24. H-H = 1.5, 7.4 Hz) indicative of a certain through-space interaction between the two platinum-bound aromatic rings.