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Volumn 36, Issue 13, 2003, Pages 4672-4674

Novel anionic thermally latent initiating systems: Controlled anionic polymerization of glycidyl phenyl ether with silylated nucleophiles/inorganic fluoride salts system

Author keywords

[No Author keywords available]

Indexed keywords

LATENT INITIATING SYSTEMS;

EID: 0038102670     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma0301350     Document Type: Article
Times cited : (15)

References (47)
  • 12
    • 0038138330 scopus 로고
    • Alien, N. S., Ed.; Applied Science Publishers: Essex, England; Chapter 1
    • (b) Crivello, J. V. Developments in Polymer Photochemistry; Alien, N. S., Ed.; Applied Science Publishers: Essex, England, 1981; Chapter 1.
    • (1981) Developments in Polymer Photochemistry
    • Crivello, J.V.1
  • 43
    • 0034706338 scopus 로고    scopus 로고
    • We have reported several anionic thermally latent initiating systems: (a) Kim, M.; Sanda, F.; Endo, T. Tetrahedron Lett. 2000, 41, 7487.
    • (2000) Tetrahedron Lett. , vol.41 , pp. 7487
    • Kim, M.1    Sanda, F.2    Endo, T.3
  • 46
    • 0037957862 scopus 로고
    • Paquette, L. A., Ed.; John Willy & Sons: New York
    • Polymerizations by CsF-mediated desilylation of silylated nucleophiles as a thermally latent anionic initiating system have not been investigated, as far as we know, although there are several reports about desilylation by using CsF: Friestad, G. K.; Branchaud, B. P. In Encyclopedia of Reagents for Organic Synthesis; Paquette, L. A., Ed.; John Willy & Sons: New York, 1995; Vol. 2, p 1042.
    • (1995) Encyclopedia of Reagents for Organic Synthesis , vol.2 , pp. 1042
    • Friestad, G.K.1    Branchaud, B.P.2
  • 47
    • 0038477275 scopus 로고    scopus 로고
    • note
    • Figure 1 shows that the present polymerization of GPE was carried out over 80 °C. However, similar polymerization also proceeds at 65 °C, although long polymerization time (ca. 24 h) was required.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.