Synthesis and photoactivity of novel 5-arylthianthrenium salt cationic photoinitiators

Journal of Polymer Science, Part A: Polymer Chemistry

Volumn 40, Issue 20, 2002, Pages 3465-3480

  Crivello, James V ^a   Ma, Junqing ^a   Jiang, Faming ^a  

^a Research Rensselaer Polytechnic Institute   (United States)

Author keywords

9 arylthianthrenium salts; Cationic polymerization; Epoxide monomers; Photochemistry; Photoinitiated cationic polymerization; Photoinitiators; Triarylsulfonium salts

Indexed keywords

CATIONIC POLYMERIZATION; EPOXY RESINS; FOURIER TRANSFORM INFRARED SPECTROSCOPY; MONOMERS; PHOTOCHEMICAL REACTIONS; PHOTOSENSITIZERS; SALTS; SYNTHESIS (CHEMICAL); ULTRAVIOLET SPECTROSCOPY;

ARYLTHIANTHRENIUM SALT; ELECTRON TRANSFER PHOTOSENSITIZER; EPOXIDE MONOMER; FOURIER TRANSFORM REAL-TIME INFRARED SPECTROSCOPY; PHOTOINITIATOR; TRIARYLSULFONIUM SALT;

INITIATORS (CHEMICAL);

SYNTHESIS;

EID: 0037108579     PISSN: 0887624X     EISSN: None     Source Type: Journal    
DOI: 10.1002/pola.10425     Document Type: Article

References (30)

1. Crivello, J. V.; Lam, J. H. L. J Polym Sci Polym Chem Ed 1979, 17, 977.
2. Crivello, J. V. UV Curing Science and Technology; Pappas, S. P., Ed.; Technology Marketing Corp.: Stamford, CT, 1978; Chapter 2, p 24.
3. Crivello, J. V. Ring-Opening Polymerization; Brunelle, D. J., Ed.; Hanser: Munich, 1993; p 157.
4. Crivello, J. V. J Polym Sci Part A: Polym Chem 1999, 37, 4241.
5. Crivello, J. V.; Varlemann, U. J Polym Sci Part A: Polym Chem 1995, 33, 2463.
6. Pitt, H. M. U.S. Patent 2,807,648, May 6, 1958
7. Pitt, H. M. Chem Abstr 1958, 52, 2910d.
8. Holland, C. Am Ink Maker 2001, 79, 12.
9. Gilman, H.; Swayampati, D. R. J Am Chem Soc 1955, 77, 3387.
10. Crivello, J. V.; Liu, S. J Polym Sci Part A: Polym Chem 2000, 38, 389.
11. Gilman, H.; Swayampati, D. R. J Am Chem Soc 1956, 78, 2163.
12. Glass, H. B.; Reid, E. E. J Am Chem Soc 1929, 51, 3428.
13. Breslow, D. S.; Skolnik, H. Heterocyclic Compounds: Multi-Sulfur and Sulfur and Oxygen Five- and Six-Membered Heterocycles; Interscience: New York, 1966; p 1155.
14. Shimomura, O.; Tomita, I.; Endo, T. J Polym Sci Part A: Polym Chem 1999, 37, 127.
15. Dougherty, G.; Hammond, P. D. J Am Chem Soc 1939, 61, 80.
16. Kim, K.; Bae, H. K. Bull Korean Chem Soc 1987, 8, 165
17. Kim, K.; Bae, H. K. Chem Abstr 1988, 108, 56007.
18. Crivello, J. V.; Lee, J. L. Polym J 1985, 17, 73.
19. Cameron, J. F.; Adams, T.; Orellana, A. J.; Rajaratnam, M. M.; Sinta, R. Proc SPIE-Int Soc Opt Eng 1997, 1997, 473.
20. Akhtar, S. R.; Crivello, J. V.; Lee, J. L. J Org Chem 1990, 2, 732.
21. Akhtar, S. R.; Crivello, J. V.; Lee, J. L.; Schmitt, M. L. Chem Mater 1990, 55, 4222.
22. Crivello, J. V. U.S. Patent 5,012,001, Apr. 30, 1991
23. Crivello, J. V. Chem Abstr 1986, 105, 190652w.
24. Kato, S.; Sasaki, S. Polym Prepr (Am Chem Soc Div Polym Chem) 2001, 42, 729.
25. Decktar, J. L.; Hacker, N. P. J Chem Soc Chem Commun 1987, 1592.
26. Saeva, F. D. J Chem Soc Chem Commun 1987, 00, 37.
27. Saeva, F. D.; Morgan, B. P.; Luss, H. R. J Org Chem 1985, 50, 4360.
28. Gomurasvili, Z.; Crivello, J. V. J Polym Sci Part A: Polym Chem 2001, 39, 1187.
29. Hua, Y.; Jiang, F.; Crivello, J. V. Chem Mater, in press.
30. Crivello, J. V.; Hua, Y.; Gomurashvili, Z. Macromol Chem Phys 2001, 202, 2133.